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  • 1
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    Wiley ; 2013
    In:  International Journal of Quantum Chemistry Vol. 113, No. 19 ( 2013-10-05), p. 2181-2199
    In: International Journal of Quantum Chemistry, Wiley, Vol. 113, No. 19 ( 2013-10-05), p. 2181-2199
    Kurzfassung: Coherence is a collective property that is present in Bose–Einstein condensates (BEC), an example of which when charged is superconductivity (SC). Coherence is also believed to be present to a degree in highly efficient energy transfer in certain biological systems. Attributes of coherent systems are examined in BEC, superfluidity and Bardeen, Cooper, and Schrieffer SC and a laser in part 1. Part 2 consists of examination of various proposals for coherence including “emergent coherent systems” where there may be coherence but no phase transition. We discuss “cold” atomic gases, the Casimir effect, an extended version of Förster's resonance energy transfer, Fröhlich's model, exciton‐coupled quantum wells, and conceptually “old” polaritons rejuvenated by new developments. A discussion about highly efficient energy transfer in photosynthesis along with our proposal for a possible new model for this system is the last of the examples. We finish with a discussion about emergent coherent systems and attempt to classify the examples of parts 1 and 2. © 2013 Wiley Periodicals, Inc.
    Materialart: Online-Ressource
    ISSN: 0020-7608 , 1097-461X
    URL: Issue
    Sprache: Englisch
    Verlag: Wiley
    Publikationsdatum: 2013
    ZDB Id: 1475014-4
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  • 2
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    Wiley ; 2007
    In:  International Journal of Quantum Chemistry Vol. 107, No. 15 ( 2007-01), p. 3013-3027
    In: International Journal of Quantum Chemistry, Wiley, Vol. 107, No. 15 ( 2007-01), p. 3013-3027
    Kurzfassung: The pioneering works by Eagles, Leggett, and Nozieres/Schmitt‐Rink [Eagles, Phys Rev, 1969, 186, 456; Leggett, In: Modern Trends in the Theory of Condensed Matter, Springer‐Verlag: Berlin, 1980; Nozieres and Schmitt‐Rink, Low Temp Phys, 1985, 59, 980] (reviewed and augmented by Randeria [Randeria, Bose‐Einstein Condensation, Cambridge University Press, Cambridge, 1995, p 255] ) emphasize that in the limits of the models studied both at T = 0 and T ≠ 0, the “cross‐over” from a BCS‐type to a BEC‐type superconductor is continuous. The BCS and BEC “end points” seem to be well‐established. However, in the intermediate region—home to fulleride and high temperature superconductors—considerable extrapolation of the models must be done as there still is no exact theory. Yet, considerable current literature is devoted to what appears to be more “singular‐type phenomena” such as quantum critical points, “stripe” formation, insulator to superconductor phase transitions, loss of validity of the Fermi liquid theory, etc. Using a connection we have made with “cold” atom fermion‐boson crossover theory [Chen, Stajic, Levin, 2005, e‐print cond‐mat/0508603], we can establish that the resonance previously discussed [Squire and March, Int J Quant Chem, 2006, 106, 3343] is a result of the crossing of the fermion band by the boson band. While the ground state appears to remain continuous, the paired energy gap becomes transformed. We discuss features of the resonance and the experimentally observed pre‐formed “BEC Cooper pair” formation, essential to the boson‐fermion resonance theory. In addition some of the various singular phenomena discussed above can be put more into perspective. Finally, in both limits the relation of characteristic lengths to the inverse Fermi momentum is strongly emphasized, as is the role of the chemical potential near the pseudogap regime. © 2007 Wiley Periodicals, Inc. Int J Quantum Chem, 2007
    Materialart: Online-Ressource
    ISSN: 0020-7608 , 1097-461X
    URL: Issue
    Sprache: Englisch
    Verlag: Wiley
    Publikationsdatum: 2007
    ZDB Id: 1475014-4
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  • 3
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    Wiley ; 2006
    In:  International Journal of Quantum Chemistry Vol. 106, No. 15 ( 2006-01), p. 3343-3363
    In: International Journal of Quantum Chemistry, Wiley, Vol. 106, No. 15 ( 2006-01), p. 3343-3363
    Kurzfassung: We propose a microscopic mechanism for superconductivity in an alkali‐metal doped fulleride. Support is given for the notion that a fulleride doped with two electrons exhibits Wigner‐like correlations. Doping a third electron into this system leads to a transition to superconductivity. The present work has expanded interactions to include not only Wigner‐like correlations between electrons, but also phonons and plasmons. The strength and influence of the numerous interactions are discussed. In the latter context, a “Marel plot” is briefly considered along with electron energy loss measurements. Lastly, we propose that a “soft” electron‐pair quasi‐particle is involved in pairing. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2006
    Materialart: Online-Ressource
    ISSN: 0020-7608 , 1097-461X
    URL: Issue
    Sprache: Englisch
    Verlag: Wiley
    Publikationsdatum: 2006
    ZDB Id: 1475014-4
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  • 4
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    Wiley ; 2012
    In:  International Journal of Quantum Chemistry Vol. 112, No. 1 ( 2012-01), p. 89-98
    In: International Journal of Quantum Chemistry, Wiley, Vol. 112, No. 1 ( 2012-01), p. 89-98
    Kurzfassung: Quasiparticles and collective effects may have seemed exotic when first proposed in the 1930s, but their status has blossomed with their confirmation by today's sophisticated experiment techniques. Evidence has accumulated about the interactions of, say, magnons and rotons and with each other and also other quasiparticles (QPs). We briefly review the conjectures of their existence necessary to provide quantitative agreement with experiment which in the early period was their only reason for existence. Phase transitions in the Anderson model, the Kondo effect, roton–roton interactions, and highly correlated systems such as helium‐4, the quantum Hall effect, and Bose–Einstein condensates are discussed. Some insulator and superconductor theories seem to suggest that collective interactions of several QPs may be necessary to explain the behavior. We conclude with brief discussions of the possibility of using the Grüneisen parameter to detect quantum critical points and some background on bound states emerging from the continuum. Finally, we present a summary and conclusions and also discuss possible future directions. © 2011 Wiley Periodicals, Inc. Int J Quantum Chem, 2012
    Materialart: Online-Ressource
    ISSN: 0020-7608 , 1097-461X
    URL: Issue
    Sprache: Englisch
    Verlag: Wiley
    Publikationsdatum: 2012
    ZDB Id: 1475014-4
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  • 5
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    Wiley ; 2005
    In:  International Journal of Quantum Chemistry Vol. 105, No. 6 ( 2005-01), p. 883-897
    In: International Journal of Quantum Chemistry, Wiley, Vol. 105, No. 6 ( 2005-01), p. 883-897
    Kurzfassung: The present study has two prime aims. The first is to attempt an explanation of the recent experiment on a high T c cuprate in which the superconductivity is suppressed by an applied magnetic field of 58 tesla (T). We propose an interpretation in terms of a specific quantum transition, namely a magnetically induced Wigner solid of charge carriers. Second, we explore similarities between superconductivity in alkali‐doped fullerides and the high T c cuprates based on an interpretation of Uemura‐type plots. A phase diagram for alkali‐doped fullerides is proposed that contains possible universal quantum phase transitions. Evidence is presented that suggests the superconducting phase is located between Wigner solids of charge carriers in fullerides at higher and lower doping at T = 0. Implications are discussed. © 2005 Wiley Periodicals, Inc. Int J Quantum Chem, 2005
    Materialart: Online-Ressource
    ISSN: 0020-7608 , 1097-461X
    URL: Issue
    Sprache: Englisch
    Verlag: Wiley
    Publikationsdatum: 2005
    ZDB Id: 1475014-4
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  • 6
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    Wiley ; 2008
    In:  International Journal of Quantum Chemistry Vol. 108, No. 15 ( 2008-01), p. 2819-2836
    In: International Journal of Quantum Chemistry, Wiley, Vol. 108, No. 15 ( 2008-01), p. 2819-2836
    Kurzfassung: There continues to be enormous interest in the BCS to BEC transition. While the BCS and BEC “end points” seem to be well‐established, in the intermediate region—home to fulleride and high temperature superconductors—considerable extrapolation of the models must be done as there still is no exact theory. Last year we reported a revealing reinterpretation of the Boson–Fermion model (BFM) by comparing it to the “cold” atom formulation. While the ground and singly excited states appear to remain continuous in all models we have examined, the collective modes due to a Feshbach resonance (tuned by doping) cause a breakdown of the Migdal theorem, thereby transforming the nature of the superconductivity. As a result of vertex corrections there is a fundamental change in the nature of the superconductivity due to the formation of “preformed pairs” as the previously suggested location (Squire and March, Int J Quantum Chem 2007, 107, 3013) of a quantum critical point in the fulleride phase diagram is passed. The result is a quantum phase transition between BCS and BEC superconductivity (SC) in the BFM. We discuss features of the resonance and the experimentally observed preformed pair formation in fullerides, essential to the BFM, and often speculated since the work of Nozieres and Schmitt–Rink (J Low Temp Phys 1985, 59, 980). Here we present arguments to establish a model of the preformed pair which can be favorably compared with a circular charge density wave (CDW) isolated on a fulleride molecule due to Coulomb splitting of the Jahn–Teller active H g vibrational modes. Our conclusions are: (1) the doping of two electrons into triply degenerate t 1u orbitals results in the experimentally observed singlet state (CDW); and (2) this CDW (preformed pair) results in suppression of BCS SC and enables the Feshbach resonance. © 2008 Wiley Periodicals, Inc. Int J Quantum Chem, 2008
    Materialart: Online-Ressource
    ISSN: 0020-7608 , 1097-461X
    URL: Issue
    Sprache: Englisch
    Verlag: Wiley
    Publikationsdatum: 2008
    ZDB Id: 1475014-4
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  • 7
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    Elsevier BV ; 2005
    In:  Physics Letters A Vol. 344, No. 5 ( 2005-9), p. 383-386
    In: Physics Letters A, Elsevier BV, Vol. 344, No. 5 ( 2005-9), p. 383-386
    Materialart: Online-Ressource
    ISSN: 0375-9601
    RVK:
    Sprache: Englisch
    Verlag: Elsevier BV
    Publikationsdatum: 2005
    ZDB Id: 1466603-0
    ZDB Id: 208865-4
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  • 8
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    Wiley ; 2010
    In:  International Journal of Quantum Chemistry Vol. 110, No. 15 ( 2010-12), p. 2808-2822
    In: International Journal of Quantum Chemistry, Wiley, Vol. 110, No. 15 ( 2010-12), p. 2808-2822
    Kurzfassung: We present a model for cuprate superconductivity based on the identification of an experimentally detected “local superconductor” as a charge 2 fermion pairing in a circular, stationary density wave. This wave acts like a highly correlated local “boson” satisfying a modified Cooper problem with additional correlation stabilization relative to the separate right‐ and left‐handed density waves composing it. This local “boson” could be formed in a two‐bound roton‐like manner; it has Fermion statistics. Delocalized superconductive pairing (superconductivity) is achieved by a Feshbach resonance of two unpaired holes (electrons) resonating with a virtual energy level of the bound pair state of the local “boson” as described by the previously discussed Boson‐Fermion‐Gossamer (BFG) model. The spin‐charge order interaction offers a microscopic basis for the cuprate T c ' s . The spin‐charge interaction correlates T c with experimental inelastic neutron and electron Raman scattering is proposed, based on the energy of the virtual bound pair. These and other modifications discussed, suggest a BFG‐based microscopic explanation for the entire cuprate superconductivity dome shape. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2010
    Materialart: Online-Ressource
    ISSN: 0020-7608 , 1097-461X
    URL: Issue
    Sprache: Englisch
    Verlag: Wiley
    Publikationsdatum: 2010
    ZDB Id: 1475014-4
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  • 9
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    Elsevier BV ; 2006
    In:  Physics Letters A Vol. 355, No. 6 ( 2006-07), p. 494-
    In: Physics Letters A, Elsevier BV, Vol. 355, No. 6 ( 2006-07), p. 494-
    Materialart: Online-Ressource
    ISSN: 0375-9601
    RVK:
    Sprache: Englisch
    Verlag: Elsevier BV
    Publikationsdatum: 2006
    ZDB Id: 1466603-0
    ZDB Id: 208865-4
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  • 10
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    Wiley ; 2009
    In:  International Journal of Quantum Chemistry Vol. 109, No. 15 ( 2009-12), p. 3516-3532
    In: International Journal of Quantum Chemistry, Wiley, Vol. 109, No. 15 ( 2009-12), p. 3516-3532
    Kurzfassung: There has been considerable effort expended toward understanding high temperature superconductors (HTSC), and more specifically the cuprate phase diagram as a function of doping level. Yet, the only agreement seems to be that HTSC is an example of a strongly correlated material where Coulomb repulsion plays a major role. This manuscript proposes a model based on a Feshbach resonance pairing mechanism and competing orders. An initial BCS‐type superconductivity at high doping is suppressed in the two particle channel by a localized preformed pair (PP) (Nozieres and Schmitt‐Rink, J Low Temp Phys, 1985, 59, 980) (circular density wave) creating a quantum critical point. As doping continues to diminish, the PP then participates in a Feshbach resonance complex that creates a new electron (hole) pair that delocalizes and constitutes HTSC and the characteristic dome (Squire and March, Int J Quantum Chem, 2007, 107, 3013; 2008, 108, 2819). The resonant nature of the new pair contributes to its short coherence length. The model we propose also suggests an explanation (and necessity) for an experimentally observed correlated lattice that could restrict energy dissipation to enable the resonant Cooper pair to move over several correlation lengths, or essentially free. The PP density wave is responsible for the pseudogap as it appears as a “localized superconductor” since its density of states and quasiparticle spectrum are similar to those of a superconductor (Peierls–Fröhlich theory), but with no phase coherence between the PP. © 2009 Wiley Periodicals, Inc. Int J Quantum Chem, 2009
    Materialart: Online-Ressource
    ISSN: 0020-7608 , 1097-461X
    URL: Issue
    Sprache: Englisch
    Verlag: Wiley
    Publikationsdatum: 2009
    ZDB Id: 1475014-4
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