In:
The Journal of Chemical Physics, AIP Publishing, Vol. 16, No. 4 ( 1948-04-01), p. 353-357
Abstract:
The reactions of atomic hydrogen, produced by a discharge, with methyl ether, acetaldehyde, and ethylene oxide have been investigated. The main products of the reactions are: from methyl ether—CH4,CO,H2O,C2H6, and HCHO;from acetaldehyde—CH4,CO, and C2H6;from ethylene oxide—CH4,CO, and CH3CHO. The mechanisms of the reactions are discussed in detail and it is concluded that the primary reactions are: H+CH3OCH3→H2+CH3OCH2E=7.0 kcal.H+CH3CHO →H2+CH3COE≤6.0 kcal.H+(CH2)2O →H2+C2H3OE=8.5 kcal.,and that the main secondary reactions in all cases are of the atomic cracking type: H+CH3OCH2→CH3+CH3O,H+CH3CO →CH3+CHOor →CH4+CO,H+C2H3O →CH3CHOor →CH4+CO.
Type of Medium:
Online Resource
ISSN:
0021-9606
,
1089-7690
Language:
English
Publisher:
AIP Publishing
Publication Date:
1948
detail.hit.zdb_id:
3113-6
detail.hit.zdb_id:
1473050-9
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