In:
CHIMIA, Swiss Chemical Society, Vol. 68, No. 7-8 ( 2014-08-27), p. 500-
Abstract:
The present paper describes an overview of a novel family of tridentate NHC pincer ligand in which two phenoxide moieties are directly connected to the nitrogen atoms of a central N-heterocyclic carbene. It was envisioned that such a structure might be suitable for coordination to a
variety of metal centers across the periodic table, including oxophilic metals. Various metal complexes bearing such ligand are indeed readily accessible in high yields via straightforward routes. Interestingly, a robust zirconium–NHC complex was found to polymerize rac-lactide in a highly controlled, living and stereoselective manner to afford heterotactic PLA.
Type of Medium:
Online Resource
ISSN:
2673-2424
,
0009-4293
DOI:
10.2533/chimia.2014.500
Language:
Unknown
Publisher:
Swiss Chemical Society
Publication Date:
2014
detail.hit.zdb_id:
2179192-2
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