In:
Chemistry – A European Journal, Wiley, Vol. 22, No. 52 ( 2016-12-23), p. 18817-18823
Abstract:
Our studies have been focused on the synthesis of N→Ga coordinated organogallium sulfides [L 1 Ga(μ‐S)] 3 ( 1 ) and [L 2 Ga(μ‐S)] 2 ( 2 ) containing either N,C,N‐ or C,N‐chelating ligands L 1 or L 2 (L 1 is {2,6‐(Me 2 NCH 2 ) 2 C 6 H 3 } − and L 2 is {2‐(Et 2 NCH 2 )‐4,6‐ t Bu 2 ‐C 6 H 2 } − ). As the result of the different ligands, compounds 1 and 2 differ mutually in their structure. To change the Ga/S ratio, unusually N→Ga coordinated organogallium tetrasulfide L 1 Ga(κ 2 ‐S 4 ) ( 3 ) was prepared and the unprecedented complex [{2‐[CH{(CH 2 ) 3 CH 3 }(μ‐OH)]‐6‐CH 2 NMe 2 }C 6 H 3 ]GaS ( 4 ) was also isolated as the minor by‐product of the reaction. Compounds 1 – 3 were further studied as potential single‐source precursors for amorphous GaS thin film deposition by spin‐coating.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.201604190
Language:
English
Publisher:
Wiley
Publication Date:
2016
detail.hit.zdb_id:
1478547-X
Bookmarklink