In:
The Journal of Chemical Physics, AIP Publishing, Vol. 89, No. 8 ( 1988-10-15), p. 4646-4653
Abstract:
The laser induced fluorescence spectra of the C–X transitions of HgRg (Rg=Ne, Ar, Kr, and Xe) van der Waals complexes formed in a supersonic jet have been observed in the longer wavelength side of the Hg(1P1−1S0) resonance transition by use of a tunable vacuum ultraviolet laser, which is generated by the two-photon resonant four-wave sum mixing in Sr vapor. On the basis of vibrational quantum numbers assigned to the upper levels of the observed C–X transitions,potential parameters of the C state are determined. The interatomic potentials for the C state are well approximated by a Morse function and the dissociation energies for HgNe, HgAr, HgKr, and HgXe are 89, 486, 1410, and 3463 cm−1 , respectively.
Type of Medium:
Online Resource
ISSN:
0021-9606
,
1089-7690
Language:
English
Publisher:
AIP Publishing
Publication Date:
1988
detail.hit.zdb_id:
3113-6
detail.hit.zdb_id:
1473050-9
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