In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 635, No. 9-10 ( 2009-07), p. 1306-1312
Abstract:
The neutral pentacoordinate silicon(IV) complexes 3 ( Si ClO 2 NC skeleton), 4 ( Si O 3 NC), 5 ( Si O 2 N 2 C), and 6 ( Si ClON 2 C) were synthesized. Compounds 3 – 6 contain a tridentate dianionic O , N , O ( 3 – 5 ) or O , N , N ligand ( 6 ), a phenyl ligand, and a (pseudo‐)halogeno ( 3 , 5 , 6 ) or trifluoromethanesulfonato ligand ( 4 ). Compounds 3 – 6 were characterized by single‐crystal X‐ray diffraction and solid‐state and solution NMR spectroscopy. According to these studies, the coordination number of the silicon atom in the solid complexes 3 – 6 is retained in solution.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v635:9/10
DOI:
10.1002/zaac.200900108
Language:
English
Publisher:
Wiley
Publication Date:
2009
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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