In:
Angewandte Chemie, Wiley, Vol. 130, No. 41 ( 2018-10-08), p. 13653-13657
Abstract:
A nonheme {FeNO} 6 complex, [Fe(NO)(N3PyS)] 2+ , was synthesized by reversible, one‐electron oxidation of an {FeNO} 7 analogue. This complex completes the first known series of sulfur‐ligated {FeNO} 6–8 complexes. All three {FeNO} 6–8 complexes are readily interconverted by one‐electron oxidation/reduction. A comparison of spectroscopic data (UV/Vis, NMR, IR, Mössbauer, X‐ray absorption) provides a complete picture of the electronic and structural changes that occur upon {FeNO} 6 –{FeNO} 8 interconversion. Dissociation of NO from the new {FeNO} 6 complex is shown to be controlled by solvent, temperature, and photolysis, which is rare for a sulfur‐ligated {FeNO} 6 species.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v130.41
DOI:
10.1002/ange.201806146
Language:
English
Publisher:
Wiley
Publication Date:
2018
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505872-7
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