In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2003, No. 6 ( 2003-03), p. 1058-1071
Abstract:
The decomposition of ammonium heptamolybdate (AHM, (NH 4 ) 6 Mo 7 O 24 ×4H 2 O) was studied in situ by X‐ray diffraction and X‐ray absorption spectroscopy, as well as by thermal analysis (TG/DTA). Decomposition conditions such as reactant atmospheres, (20% oxygen, 5% propene, 5% hydrogen, pure helium, and static air), heating rates, and gas flow rates were varied to investigate their influence on the decomposition process. The results obtained show that the reaction pathway is affected by the partial pressures of the gas‐phase decomposition products. The partial pressures of the decomposition products, water and ammonia, at a given temperature, is influenced mainly by the reactant gas flow rate and the heating rate. Lowering the partial pressures of ammonia and water inhibits the crystallization of the intermediate ammonium tetramolybdate (ATM), and promotes the formation of the intermediate hexagonal MoO 3 . The decomposition pathway under low gas phase product partial pressure is: (i) AHM; (ii) (ca. 335 K) X‐ray amorphous phase; (iii) (ca. 520 K) hexagonal MoO 3 ; (iv) (ca. 650 K) the products, which depend on the reactant atmosphere, are mixtures of highly disordered Mo 4 O 11 , and/or α‐MoO 3 . Under different conditions the decomposition pathway is: (i) AHM; (ii) (ca. 350 K) X‐ray amorphous phase; (iii) (ca. 470 K) ATM; (iv) (ca. 570 K) hexagonal MoO 3 + α‐MoO 3 ; (ca. 650 K) α‐MoO 3 . Under a hydrogen containing atmosphere, a peculiar decomposition pathway is observed: an intermediate MoO 3 with an unusual texture is formed prior to the reduction to MoO 2 and the consecutive formation of orthorhombic Mo 4 O 11 . (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2003:6
DOI:
10.1002/ejic.200390138
Language:
English
Publisher:
Wiley
Publication Date:
2003
detail.hit.zdb_id:
1475009-0
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