In:
Angewandte Chemie, Wiley, Vol. 135, No. 39 ( 2023-09-25)
Abstract:
Water and other small molecules frequently coordinate within metal‐organic frameworks (MOFs). These coordinated molecules may actively engage in mass transfer, moving together with the transport molecules, but this phenomenon has yet to be examined. In this study, we explore a unique water transfer mechanism in UTSA‐280, where an incoming water molecule can displace a coordinated molecule for mass transfer. We refer to this process as the “knock‐off” mechanism. Despite UTSA‐280 possessing one‐dimensional channels, the knock‐off transport enables water movement along the other two axes, effectively simulating a pseudo‐three‐dimensional mass transfer. Even with a relatively narrow pore width, the knock‐off mechanism enables a high water flux in the UTSA‐280 membrane. The knock‐off mechanism also renders UTSA‐280 superior water/ethanol diffusion selectivity for pervaporation. To validate this unique mechanism, we conducted 1 H and 2 H solid‐state NMR on UTSA‐280 after the adsorption of deuterated water. We also derived potential energy diagrams from the density functional theory to gain atomic‐level insight into the knock‐off and the direct‐hopping mechanisms. The simulation findings reveal that the energy barrier of the knock‐off mechanism is marginally lower than the direct‐hopping pathway, implying its potential role in enhancing water diffusion in UTSA‐280.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v135.39
DOI:
10.1002/ange.202309874
Language:
English
Publisher:
Wiley
Publication Date:
2023
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