In:
Angewandte Chemie, Wiley, Vol. 129, No. 11 ( 2017-03-06), p. 3126-3130
Abstract:
Herein, the first acceptorless dehydrogenation of tetrahydroquinolines (THQs), indolines, and other related N‐heterocycles, by merging visible‐light photoredox catalysis and cobalt catalysis at ambient temperature, is described. The potential applications to organic transformations and hydrogen‐storage materials are demonstrated. Primary mechanistic investigations indicate that the catalytic cycle occurs predominantly by an oxidative quenching pathway.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v129.11
DOI:
10.1002/ange.201612486
Language:
English
Publisher:
Wiley
Publication Date:
2017
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1479266-7
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