In:
Acta Crystallographica Section E Crystallographic Communications, International Union of Crystallography (IUCr), Vol. 71, No. 9 ( 2015-09-01), p. 1022-1025
Abstract:
In the title structure, [Cd(C 5 H 2 N 5 ) 2 (C 3 H 7 NO) 2 ] n or [Cd(adci) 2 (DMF) 2 ] n , the Cd 2+ ion is located on a twofold rotation axis and is six-coordinated in a CdN 4 O 2 manner by four imidazole N atoms of four symmetry-related 2-amino-4,5-dicyanoimidazolate (adci) anions in the equatorial plane and by two O atoms of symmetry-related N , N -dimethylformamide (DMF) ligands in axial positions. The adci − anions bridge adjacent Cd 2+ ions [shortest Cd...Cd separation = 6.733 (3) Å] into a layered coordination polymer extending parallel to (001). The primary amino group and the non-coordinating cyano groups of adci − anions are involved in hydrogen-bonding interactions with DMF ligands to stabilize the crystal structure.
Type of Medium:
Online Resource
ISSN:
2056-9890
DOI:
10.1107/S2056989015014516
DOI:
10.1107/S2056989015014516/wm5187sup1.cif
DOI:
10.1107/S2056989015014516/wm5187Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2015
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8
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