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  • 1
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 1995
    In:  MRS Bulletin Vol. 20, No. 5 ( 1995-05), p. 29-31
    In: MRS Bulletin, Springer Science and Business Media LLC, Vol. 20, No. 5 ( 1995-05), p. 29-31
    Abstract: The remarkable properties of diamond, including its hardness, chemical inertness, high thermal conductivity, low coefficient of friction, optical transparency, and semiconducting properties, have led to considerable research in the area of diamond thin-film deposition. Diamond films have been characterized ex situ by a large number of diagnostic techniques including Raman spectroscopy, x-ray diffraction, SEM, and TEM. In situ diagnostics, which can provide information in real time as the film is growing, are less common. Laser-reflectance interferometry (LRI) has been used to monitor the growth of diamond films in situ . The technique involves measuring the intensity of a laser beam reflected from the substrate surface on which the film is growing. The reflected beam is the sum of beams reflected by the gas-diamond interface and the diamond-silicon interface. Oscillations in the reflectivity are observed as the film grows because of interference between the reflected beams. Each oscillation indicates an increase in film thickness of λ/2 n , where λ is the laser wavelength and n is the index of refraction of the film. If the index of refraction of the film is known, the thickness and growth rate can be determined in situ . For LRI measurements with 632.8-nm-wavelength HeNe lasers, the index of refraction of diamond films has been found to be within 10% of the bulk diamond value of 2.4. Each oscillation therefore indicates an increase in film thickness of 0.13 μm. The reflectivity measured by LRI is also affected by scattering because of surface roughness.
    Type of Medium: Online Resource
    ISSN: 0883-7694 , 1938-1425
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 1995
    detail.hit.zdb_id: 2749565-6
    detail.hit.zdb_id: 2136359-6
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  • 2
    Online Resource
    Online Resource
    AIP Publishing ; 1996
    In:  Journal of Applied Physics Vol. 79, No. 7 ( 1996-04-01), p. 3541-3547
    In: Journal of Applied Physics, AIP Publishing, Vol. 79, No. 7 ( 1996-04-01), p. 3541-3547
    Abstract: A model is presented to interpret in situ laser reflectance interferometry (LRI) measurements of film growth. The model uses no adjustable parameters and measures film thickness, growth rate, attenuation, and root-mean-square (rms) surface roughness in situ and in real time. For the particular case of diamond film growth on silicon substrates, it is shown that the assumptions of the model are satisfied, and that film properties determined in situ by LRI and by various means ex situ are in good agreement. With this model, the evolution of diamond film properties are followed under typical diamond growth conditions using mixtures of CH4 and H2. In agreement with texture formation models, the growth rate and surface roughness were observed to increase as film growth progressed. The growth rate was found to be proportional to CH4 fraction for CH4 fractions less than 8.5%. At higher CH4 fractions, the growth rate decreased and significant attenuation was observed.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1996
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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