Format:
Online-Ressource
ISSN:
1521-3919
Content:
Abstract: The RAFT radical polymerization of vinyl monomers in supercritical carbon dioxide was modeled using the Predici® simulation package. The sensitivity of polymerization responses on formulation and process variables was analyzed. The simulations were carried out using kinetic and physical parameters corresponding to the polymerization of methyl methacrylate in supercritical carbon dioxide, using AIBN as initiator, at 65 °C and 200 bar, and using values of the addition and fragmentation kinetic rate constants of a “typical” RAFT agent, as reference conditions. This is the first report in the literature addressing the modeling or simulation of RAFT polymerization in supercritical carbon dioxide.
In:
volume:17
In:
number:6
In:
year:2008
In:
pages:280-289
In:
extent:10
In:
Macromolecular theory and simulations, Weinheim : Wiley-VCH, 1992-, 17, Heft 6 (2008), 280-289 (gesamt 10), 1521-3919
Language:
English
DOI:
10.1002/mats.200800006
URN:
urn:nbn:de:101:1-2023080209112494917904
URL:
https://doi.org/10.1002/mats.200800006
URL:
https://nbn-resolving.org/urn:nbn:de:101:1-2023080209112494917904
URL:
https://d-nb.info/1297975170/34
URL:
https://doi.org/10.1002/mats.200800006
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