Format:
1 online resource (769 pages)
Edition:
2., rev. ed.
ISBN:
9783527683789
,
9783527683802
Content:
Intro -- Principles and Practice of Heterogeneous Catalysis -- Contents -- Preface -- Chapter 1 Setting the Scene -- 1.1 Prologue: Advances since the Early 1990s -- 1.2 Introduction -- 1.2.1 Selectivity of Catalysts -- 1.3 Perspectives in Catalysis: Past, Present and Future -- 1.3.1 Applied Catalysis since the 1940s -- 1.3.2 Some Current Trends in Applied Catalysis -- 1.3.2.1 Auto-Exhaust Catalysts -- 1.3.2.2 Catalysts in Electrochemistry and Photoelectrochemistry -- 1.3.2.3 Immobilized Metals -- 1.3.2.4 Immobilized Enzymes and Cells: Present and Future -- 1.3.2.5 Ribozymes -- 1.4 Definition of Catalytic Activity -- 1.4.1 Magnitude of Turnover Frequencies and Active Site Concentrations -- 1.4.2 Volcano Plots -- 1.4.3 Evolution of Important Concepts and Techniques in Heterogeneous Catalysis -- 1.4.3.1 Mechanistic Insights from Isotopic Labelling -- 1.4.3.2 Concepts from Organometallic Chemistry -- 1.5 Key Advances in Recent Theoretical Treatments: Universability in Heterogeneous Catalysis -- 1.5.1 Some Major Current Developments in Heterogeneous Catalysis -- 1.6 Milestones Reached in Industrial Catalysis in the Twentieth Century, and Some Consequential Challenges -- Problems -- References -- Further Reading -- Chapter 2 The Fundamentals of Adsorption: Structural and Dynamical Considerations, Isotherms and Energetics -- 2.1 Catalysis Must Always Be Preceded by Adsorption -- 2.1.1 Physical Adsorption, Chemisorption and Precursor States -- 2.2 The Surfaces of Clean Solids are Sometimes Reconstructed -- 2.3 There Are Many Well-Defined Kinds of Ordered Adlayers -- 2.4 Adsorption Isotherms and Isobars -- 2.4.1 The Empirical Facts -- 2.4.2 Information That Can Be Gleaned from Isotherms -- 2.4.3 Adsorption Is Almost Invariably Exothermic -- 2.5 Dynamical Considerations -- 2.5.1 Residence Times -- 2.5.2 Rates of Adsorption.
Content:
This long-awaited second edition of the successful introduction to the fundamentals of heterogeneous catalysis is now completely revised and updated. Written by internationally acclaimed experts, this textbook includes fundamentals of adsorption, characterizing catalysts and their surfaces, the significance of pore structure and surface area, solid-state and surface chemistry, poisoning, promotion, deactivation and selectivity of catalysts, as well as catalytic process engineering. A final section provides a number of examples and case histories. With its color and numerous graphics plus references to help readers to easily find further reading, this is a pivotal work for an understanding of the principles involved. Professor Sir John Meurig Thomas, FRS, FREng, Former Head of Physical Chemistry , University of Cambridge, is one of the most renowned researcher in the field of heterogeneous catalysis and solid state chemistry. He has been awarded the Davy Medal, the Messel Gold Medal, the Willard Gibbs Gold Medal, U.S. Presidential Green Chemistry Challenge Award, the Linus Pauling Gold Medal and many others. He is the author of over a thousand research papers on the materials and surface chemistry of solids, and over 100 review articles on science, education and cultural issues and the co-author of 30 patents. W. John Thomas, FR Eng, is Professor Emeritus of Chemical Engineering at the University of Bath.
Note:
Description based on publisher supplied metadata and other sources
,
Principles and Practice of Heterogeneous Catalysis; Contents; Preface; Chapter 1 Setting the Scene; 1.1 Prologue: Advances since the Early 1990s; 1.2 Introduction; 1.2.1 Selectivity of Catalysts; 1.3 Perspectives in Catalysis: Past, Present and Future; 1.3.1 Applied Catalysis since the 1940s; 1.3.2 Some Current Trends in Applied Catalysis; 1.3.2.1 Auto-Exhaust Catalysts; 1.3.2.2 Catalysts in Electrochemistry and Photoelectrochemistry; 1.3.2.3 Immobilized Metals; 1.3.2.4 Immobilized Enzymes and Cells: Present and Future; 1.3.2.5 Ribozymes; 1.4 Definition of Catalytic Activity
,
1.4.1 Magnitude of Turnover Frequencies and Active Site Concentrations1.4.2 Volcano Plots; 1.4.3 Evolution of Important Concepts and Techniques in Heterogeneous Catalysis; 1.4.3.1 Mechanistic Insights from Isotopic Labelling; 1.4.3.2 Concepts from Organometallic Chemistry; 1.5 Key Advances in Recent Theoretical Treatments: Universability in Heterogeneous Catalysis; 1.5.1 Some Major Current Developments in Heterogeneous Catalysis; 1.6 Milestones Reached in Industrial Catalysis in the Twentieth Century, and Some Consequential Challenges; Problems; References; Further Reading
,
Chapter 2 The Fundamentals of Adsorption: Structural and Dynamical Considerations, Isotherms and Energetics2.1 Catalysis Must Always Be Preceded by Adsorption; 2.1.1 Physical Adsorption, Chemisorption and Precursor States; 2.2 The Surfaces of Clean Solids are Sometimes Reconstructed; 2.3 There Are Many Well-Defined Kinds of Ordered Adlayers; 2.4 Adsorption Isotherms and Isobars; 2.4.1 The Empirical Facts; 2.4.2 Information That Can Be Gleaned from Isotherms; 2.4.3 Adsorption Is Almost Invariably Exothermic; 2.5 Dynamical Considerations; 2.5.1 Residence Times; 2.5.2 Rates of Adsorption
,
2.5.3 Applying Statistical Mechanics to Adsorption2.5.4 Adsorption Kinetics Can Often Be Represented by the Elovich Equation; 2.5.5 Rates of Desorption; 2.5.6 Applying Statistical Mechanics to Desorption; 2.5.7 Influence of a Precursor State on the Kinetics of Desorption; 2.6 Relating the Activation Energy to the Energy of Chemisorption. Universality in Heterogeneous Catalysis and the Brønsted-Evans-Polanyi (BEP) Relation; 2.6.1 Pareto-Optimal Catalysts; 2.7 Deriving Adsorption Isotherms from Kinetic Principles
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2.7.1 Using the Langmuir Isotherm to Estimate the Proportions of Non-dissociative and Associative Adsorption2.7.2 Other Adsorption Isotherms; 2.7.2.1 Henry's Adsorption Isotherm; 2.7.2.2 Freundlich Isotherm; 2.7.2.3 Temkin Isotherm; 2.7.2.4 Brunauer-Emmett-Teller Isotherm; 2.7.2.5 Developments from Polanyi's Adsorption Theory; 2.7.2.6 Kaganer's Isotherm and the DKR Equation; 2.7.2.7 Virial Equation of State; 2.8 Energetics of Adsorption; 2.8.1 Estimating the Binding Energies of Physically Adsorbed Species; 2.8.2 Binding Energies of Chemisorbed Species
,
2.8.3 Estimating Heats of Adsorption from Thermodynamic Data
Additional Edition:
352768378X
Additional Edition:
9783527683789
Additional Edition:
9783527314584
Additional Edition:
352731458X
Additional Edition:
Erscheint auch als Druck-Ausgabe Thomas, John M., 1932 - 2020 Principles and practice of heterogeneous catalysis Weinheim : Wiley-VCH, Verlag GmbH & Co. KGaA, 2015 352731458X
Additional Edition:
9783527314584
Additional Edition:
Print version Principles and Practice of Heterogeneous Catalysis
Language:
English
Subjects:
Chemistry/Pharmacy
Keywords:
Heterogene Katalyse
;
Heterogene Katalyse
;
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