Format:
Online-Ressource (XVI, 235 p. 128 illus., 75 illus. in color, digital)
ISBN:
9783642351334
Series Statement:
Springer Theses, Recognizing Outstanding Ph.D. Research
Content:
How can the two dimensional crystallization of colloids be used to form highly ordered colloidal monolayers on solid substrates? What application does this have in generating arrays of nanostructures? These questions are addressed in Nicolas Vogel's thesis. Vogel describes a simple preparation method for the formation of uniform colloidal crystals over large areas, which he refines to yield more complex binary and non-close-packed arrangements. These monolayers can be applied to a process termed colloidal lithography which is used to prepare high quality metallic nanostructures with tailored properties defined to suit a variety of applications. Moreover, the author describes a method used to create metallic nanodot arrays with a resolution unprecedented for colloidal lithography methods. The author also outlines methodology to embed nanoparticle arrays into the substrate, which is developed and used to design robust, re-usable biosensor platforms and nanoscale patterns of biomimetic lipid bilayer membranes. The research in this thesis has led to a large number of publications in internationally renowned journals
Note:
Includes bibliographical references
,
Surface Patterning with Colloidal Monolayers; Supervisor's Foreword; Acknowledgments; Contents; Abbreviations; 1 Introduction; References; 2 Motivation and Outline; 3 Theory; 3.1…Synthesis of Polymeric Colloidal Particles; 3.1.1 Miniemulsion Polymerization; 3.1.2 Emulsion Polymerization; 3.1.3 Summary and Comparison Between Miniemulsion and Emulsion Polymerization; 3.2…Forces at Work in Colloidal Stability and Crystallization; 3.2.1 Colloid Stability in Aqueous Dispersions; 3.2.1.1 Van der Waals Interactions; 3.2.1.2 Electrostatic Interactions; 3.2.1.3 DLVO Theory
,
3.2.2 Colloids at Interfaces3.2.2.1 Why Particles are Trapped at an Interface; 3.2.2.2 Dipole Interactions; 3.2.2.3 Capillary Forces; 3.3…Two-Dimensional Colloidal Crystallization; 3.3.1 Close-Packed Colloidal Monolayers; 3.3.1.1 Direct Assembly Methods; Evaporation Induced Methods; External Force Induced Methods; 3.3.1.2 Liquid Interface-Mediated Methods; 3.3.1.3 Summary of the Crystallization Methods; 3.3.2 Non-Close-Packed Monolayers; 3.3.2.1 Non-Close-Packed Architectures from Close-Packed Monolayers; 3.3.2.2 Non-Close-Packed Monolayers by Spin Coating
,
3.3.2.3 Direct Assembly of Non-Close-Packed Monolayers at the Oil-Water Interface3.3.3 Binary Colloidal Monolayers; 3.3.3.1 Sequential Assembly of Binary Monolayers; 3.3.3.2 Co-Assembly of Binary Monolayers; 3.4…Preparation of Nanostructures on Surfaces; 3.4.1 Colloidal Lithography; 3.4.2 Micellar Lithography; 3.4.3 Non-conventional Colloidal Lithography; 3.4.4 Applications of Colloidal Monolayers and Surface Nanostructures Fabricated by Colloidal Lithography; 3.5…Localized Surface Plasmon Resonances: A Fundamental Properties of Metallic Nanostructures
,
3.5.1 Localized Surface Plasmon Resonances3.5.2 Sensing with Localized Surface Plasmons; 3.5.3 Plasmon Hybridization; References; 4 Characterization Methods; 4.1…Atomic Force Microscopy; 4.2…Inductively Coupled Plasma Optical Emission Spectrometry; 4.3…Two-Dimensional Chemistry and Physics on a Langmuir Trough; 4.4…Scanning Electron Microscopy; 4.5…Spinning Drop Tensiometry; References; 5 Results and Discussion; 5.1…Particle Synthesis and Characterization; 5.1.1 Accurate Elemental Analysis of Metal-Containing Polymer Latexes Using Inductively Coupled Plasma: Optical Emission Spectrometry
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5.1.1.1 Introduction5.1.1.2 Results and Discussion; Synthesis of Standard Polymer Particles; Standard ICP Measurements; Size Issues; Surfactant Addition; Surface Tension; Effect of Electrolyte Addition; 5.1.1.3 Conclusion; 5.1.2 Synthesis of Metal-Complex Containing Latex Particles; 5.1.2.1 Introduction; 5.1.2.2 Incorporation of Metal Complexes by Emulsion Polymerization; Incorporation of Platinum(II)acetylacetonate; 5.1.2.3 Reasons for the Different Behavior of the Metal Complexes in Incorporation Reactions; 5.1.2.4 Incorporation of Metal Complexes by Miniemulsion Polymerization
,
Incorporation of Stoichiometric Amounts of Fe(acac)3 and Pt(acac)2
Additional Edition:
9783642351327
Additional Edition:
Buchausg. u.d.T. Vogel, Nicolas, 1981 - Surface patterning with colloidal monolayers Berlin : Springer, 2012 3642351328
Additional Edition:
9783642351327
Language:
English
Keywords:
Polymere
;
Kolloid
;
Monoschicht
;
Emulsionspolymerisation
;
Selbstorganisation
;
Nanolithografie
DOI:
10.1007/978-3-642-35133-4
URL:
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