Format:
Online-Ressource
ISSN:
1614-7065
Content:
Abstract: A series of novel optically active 1,3‐aminoalcohols based on cis‐(1R,2S)‐2‐benzamidocyclohexanecarboxylic acid and trans‐(1R,2R)‐2‐benzamidocyclohexanecarboxylic acid were synthesized and used in the asymmetric diethylzinc addition to aromatic aldehydes. Not only the enantioselectivity but also the stereochemistry of the product were controlled by the N‐substituents and the substituents on the vicinity carbon to hydroxyl group of the cis‐derivatives.
In:
volume:28
In:
number:1
In:
year:2010
In:
pages:61-68
In:
extent:8
In:
Chinese journal of chemistry, Weinheim : Wiley-VCH, 1983-, 28, Heft 1 (2010), 61-68 (gesamt 8), 1614-7065
Language:
English
DOI:
10.1002/cjoc.201090036
URN:
urn:nbn:de:101:1-2023060507444627776985
URL:
https://doi.org/10.1002/cjoc.201090036
URL:
https://nbn-resolving.org/urn:nbn:de:101:1-2023060507444627776985
URL:
https://d-nb.info/1292065281/34
URL:
https://doi.org/10.1002/cjoc.201090036
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