Kooperativer Bibliotheksverbund

UID:

Format: 1 online resource (517 pages)

ISBN: 0-12-822743-5 , 0-12-822723-0

Language: English

UID:

Format: 1 online resource (368 pages) : , illustrations

ISBN: 0-12-811652-8 , 0-12-811651-X

Note: Front Cover -- Advances in Transition-Metal Mediated Heterocyclic Synthesis -- Copyright Page -- Contents -- List of Contributors -- Foreword -- 1 Metal-Mediated Synthesis of Nonaromatic Oxacycles From Allenols -- 1.1 Introduction -- 1.2 Silver-Catalyzed Reactions -- 1.3 Gold-Catalyzed Reactions -- 1.4 Platinum-Catalyzed Reactions -- 1.5 Palladium-Catalyzed Reactions -- 1.6 Lanthanum-Catalyzed Reactions -- 1.7 Gallium-Catalyzed Reactions -- 1.8 Conclusion -- References -- 2 Intramolecular Diamination of Alkenes -- 2.1 Introduction -- 2.2 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intramolecular Vicinal Diamination of Alkenes -- 2.2.1 Palladium Catalysis -- 2.2.2 Other Metal Catalysis Using Iodine(III) Oxidants -- 2.2.3 Copper Catalysis -- 2.3 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intra-/Intermolecular Vicinal Diamination of Alkenes -- 2.3.1 Palladium Catalysis -- 2.3.2 Copper Catalysis -- 2.4 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intermolecular Vicinal Diamination of Alkenes -- 2.5 Summary and Outlook -- References -- 3 Synthesis of Heterocycles by Palladium-Catalyzed Carbonylative Reactions -- 3.1 Introduction -- 3.2 Palladium-Catalyzed Cyclocarbonylations Leading to Heterocycles -- 3.2.1 Under Oxidative Conditions -- 3.2.1.1 With Alkyne and Alkene Derivatives (Without Direct C-H Activation) -- 3.2.1.2 With Acetylenic C-H Activation -- 3.2.1.3 With Alkenylic C-H Activation -- 3.2.1.4 With Aromatic C-H Activation -- 3.2.1.5 With Aliphatic C-H Activation -- 3.2.1.6 With Diols, β-Amino Alcohols, Diamines, and Related Compounds -- 3.2.2 Under Nonoxidative Conditions -- 3.2.2.1 With Functionalized Halides -- 3.2.2.2 With Halides Together With Nucleophilic Partners -- 3.2.2.3 With Halides Together With Electrophilic Partners. , 3.2.2.4 With Halides Together With Alkenes and Imines -- 3.2.2.5 With Halides Together With Alkynes and Arynes -- 3.2.2.6 With Other Substrates -- 3.3 Palladium-Catalyzed Carbonylation Processes Leading to Heterocycles Without Incorporation of CO into the Cycle -- 3.3.1 Under Oxidative Conditions -- 3.3.1.1 Through Carbonylative Carbocyclization -- 3.3.1.2 Through Heterocyclization-Alkoxycarbonylation -- 3.3.1.3 Through Heterocyclization-Carbonylation-Cyclization Coupling -- 3.3.1.4 Through Monocarbonylation of Terminal Alkynes Followed by Intramolecular Conjugate Addition -- 3.3.2 Under Nonoxidative Conditions -- 3.3.2.1 With Halides -- 3.3.2.2 With Imine Derivatives -- 3.3.2.3 With Functionalized Alkynes -- 3.4 Conclusions and Perspectives -- References -- 4 Synthesis of Heterocyclic Compounds Based on Transition-Metal-Catalyzed Carbene Coupling Reactions -- 4.1 Introduction -- 4.2 Cyclization Prior to Metal Carbene Formation -- 4.3 Cyclization Through Other Carbene Precursors -- 4.4 Cyclization Through Reductive Elimination -- 4.5 Cyclization Through Nucleophilic Displacement -- 4.6 Synthesis of Heterocycles Through Condensation or Addition -- 4.7 Tandem Catalysis Process -- 4.8 Conclusion and Outlook -- References -- 5 Synthesis of Heterocycles With Iron Salts as Sustainable Metal Catalysts -- 5.1 Introduction -- 5.2 σ-Bond Activation -- 5.2.1 σ-Activation Via Insertion of the Molecule into the Coordination Sphere of the Metal -- 5.2.2 σ-Bond Activation Via Complexation With Functional Groups -- 5.2.2.1 Hydroxy Activation -- 5.2.2.2 Amine Activation -- 5.2.2.3 Diselenide Activation -- 5.2.2.3.1 Benzo[b]furan-Fused Selenophenes -- 5.2.2.4 Ester Activation -- 5.3 π-Bond Activation -- 5.4 Radical Reactions -- 5.5 Conclusions and Outlook -- Acknowledgments -- References -- 6 Allene Aziridination as a Tool for the Synthesis of Complex Amines. , 6.1 Introduction -- 6.2 Heterocycle Formation Via Nontransition Metal-Catalyzed Allene Amination -- 6.3 Transition Metal-Catalyzed Allene Amination Not Involving Methyleneaziridine Intermediates -- 6.4 Transition Metal-Catalyzed Allene Aziridination to Methyleneaziridines -- 6.4.1 General Features of Alkylidene or Methyleneaziridines -- 6.4.2 Intramolecular Allene Aziridination Using Carbamate Precursors -- 6.4.3 Intramolecular Allene Aziridination Using Sulfamate Precursors -- 6.4.4 Intermolecular Allene Aziridinations -- 6.5 Strategies for the Synthesis of Heterocycles Via Allene Aziridination -- 6.5.1 Nucleophilic Ring-Opening of Methyleneaziridines -- 6.5.2 Methyleneaziridine Oxidation and Rearrangement Strategies -- 6.5.3 Formation of 2-Amidoallyl Cation Intermediates -- 6.5.4 Other Reactivity of Bicyclic Methyleneaziridines -- 6.5.4.1 Synthesis of Strained Cycloalkynes -- 6.5.4.2 Synthesis of Highly Substituted Methyleneazetidines and Azetidines -- 6.6 Synthetic Applications of Allene Aziridination to Complex Molecule Synthesis -- 6.6.1 Aminosugars -- 6.6.2 Total Synthesis of (±)-Detoxinine Methyl Ester and Its Stereoisomers -- 6.6.3 Fluorinated Pyrrolidines and Unnatural Amino Acids -- 6.6.4 Aminocyclopentitol Core of Jogyamycin -- 6.7 Conclusion and Outlook -- References -- 7 Zinc-Mediated Synthesis of Heterocycles -- 7.1 Introduction -- 7.2 Zinc-Catalyzed Synthesis of Heterocycles Through Addition Reactions to Alkenes and Alkynes -- 7.2.1 Syntheses of N-Heterocycles by Zinc-Catalyzed Hydroamination Reactions -- 7.2.2 Syntheses of O-Heterocycles by Zinc-Catalyzed Hydroalkoxylation and Related Reactions -- 7.2.3 Syntheses of Heterocycles Involving Zinc-Catalyzed Addition Reactions of C-Nucleophiles to Alkynes -- 7.2.4 Other Zinc-Catalyzed Syntheses of Heterocycles Involving Transformations with Unsaturated Substrates. , 7.3 Zinc-Catalyzed Synthesis of Heterocycles Through Formal Cycloaddition Reactions -- 7.3.1 Zinc-Catalyzed Formal [4+2]-Cycloadditions -- 7.3.2 Zinc-Promoted [3+2]-Cycloadditions -- 7.3.3 Other Zinc-Promoted Cycloadditions -- 7.4 Zinc-Promoted Synthesis of Heterocycles through Condensation-Cyclization Reaction Sequences -- 7.5 Zinc-Promoted Synthesis of Heterocycles Through Michael Addition-Cyclization Reaction Sequences -- 7.6 Zinc-Catalyzed Synthesis of Cyclic Carbonate Derivatives Using CO2 -- 7.7 Summary and Outlook -- References -- 8 Controlling Selectivities in Palladium-Catalyzed Cyclization Reactions Leading to Heterocycles: From Ambiphilic Reactions... -- 8.1 Introduction -- 8.2 Chemoselectivity Control in Intramolecular Pd-Catalyzed Reactions of Amino-Tethered Aryl Halides and Ketones -- 8.3 Chemoselectivity Control in Intramolecular Pd-Catalyzed Reactions of Amino-Tethered Aryl Halides and Aldehydes -- 8.4 Chemoselectivity Control in Intramolecular Pd-Catalyzed Reactions of β-(2-Iodoanilino)esters and β-(2-Iodoanilino)carbo... -- 8.5 Catalyst-Controlled Selective Intramolecular C-H Insertion of α-Diazo Carbonyl Derivatives -- 8.6 Summary and Conclusions -- References -- Index -- Back Cover.

Language: English

UID:

Format: 1 Online-Ressource (video file 1:27:30) , Sound, Black and White

Series Statement: Socialism on Film

Content: Three stories relating to the Cuban Revolution: El Herido (The Wounded Man) set in Havana in 1957, Rebeldes (Rebels) set in the Sierra Maestra 1958 and another about the Battle of Santa Clara (December 1958)

Content: This film dramatises three different segments of the Cuban Revolution. The first episode, 'El Herido', starts in 1957 with pictures of disturbances and troops in the streets of Havana during the Batista regime. The film continues with a wounded revolutionary taking refuge at the home of a couple, Miriam and Alberto. Miriam is happy to take in the wounded freedom fighter but Alberto is uncomfortable and leaves. A series of events lead the security forces to pick up Alberto and, suspicious of him wandering the streets, he is forced to take them to his home. A firefight ensues with the hiding revolutionaries and Miriam is killed in the crossfire. Alberto escapes to be rescued by a milkman. The second episode, 'Rebeldes', sees guerrillas taking on the forces of the Batista regime in the Sierra Maestra in 1958. The section starts with an ambush of regime soldiers in which the guerrillas, all sporting long hair and beards, are able to upgrade their antique weapons by taking those of the fallen soldiers. The rest of the segment sees the guerrillas escaping the regime troops and tending to a wounded comrade they are reluctant to leave behind. The final episode, 'Santa Clara', deals with the eponymous battle in late December 1958. The revolutionaries derail a troop train and fight regime forces and armour in the town. They are aided by the civilians who supply them with Molotov cocktails. The revolutionaries eventually triumph and enter Havana. Here they are shot at by counter-revolutionaries, whom they pursue. Despite losing some of their men to these attacks, on capturing one of the perpetrators, the revolutionaries shield their captive from a lynch mob and take him away for justice

Note: Archive Reference: N-507292 , Reproduction of Cuba, 1960 35mm Comb BW pos

Language: Spanish

URL: Deutschlandweit zugänglich

Author information: Brouwer, Leo 1939-

UID:

Format: 1 CD-Audio (70 min) , digital , 1 folleto ([16] p.) , 12 cm

Content: die Vorlage enthält 11 Werke ; Flamenco ; New Flamenco ; Jazz ; Bulería de los chicos ; Recuerdo a mi Mariano / P. Ojesto. Somo esa luz ; Rumbo desconocido / P. Ojesto, Cristina González Narea. Mandela / Pablo Milanés. Tú eres la dueña de mi corazón ; Lo que eres tú pa'mí / P. Ojesto, Israel Fernández. Donde se bañó el león / Israel Fernández. Me enamoro fácilmente / Jule Styne. Reina mora / Josemi Garzón. A la luna / Miguel Montero

Note: Grabado, mezclado y masterizado en Infinity Estudios del 25 de abril al 10 de mayo de 2013

Language: Spanish

UID:

Format: xiii, 499 Seiten : , Illustrationen, Diagramme (teilweise farbig).

ISBN: 978-0-12-822723-7

Additional Edition: Erscheint auch als Online-Ausgabe ISBN 978-0-12-822743-5

Language: English

Subjects: Chemistry/Pharmacy

Keywords: Aromatizität

UID:

Format: 1 Online-Ressource (xiii, 516 Seiten) : , Illustrationen, Diagramme (teilweise farbig).

ISBN: 978-0-12-822743-5

Additional Edition: Erscheint auch als Druck-Ausgabe, Paperback ISBN 978-0-12-822723-7

Language: English

Subjects: Chemistry/Pharmacy

Keywords: Aromatizität

DOI: 10.1016/B978-0-12-822723-7.00016-9

URL: Volltext  (URL des Erstveröffentlichers)

UID:

Format: xii, 354 Seiten : , Illustrationen.

ISBN: 978-0-12-811651-7

Additional Edition: Erscheint auch als Online-Ausgabe ISBN 978-0-12-811652-4

Language: English

Subjects: Chemistry/Pharmacy

UID:

Format: 1 online resource (517 pages)

ISBN: 0-12-822743-5 , 0-12-822723-0

Language: English

UID:

Format: 1 online resource (517 pages)

ISBN: 0-12-822743-5 , 0-12-822723-0

Language: English

UID:

Format: 1 online resource (368 pages) : , illustrations

ISBN: 0-12-811652-8 , 0-12-811651-X

Note: Front Cover -- Advances in Transition-Metal Mediated Heterocyclic Synthesis -- Copyright Page -- Contents -- List of Contributors -- Foreword -- 1 Metal-Mediated Synthesis of Nonaromatic Oxacycles From Allenols -- 1.1 Introduction -- 1.2 Silver-Catalyzed Reactions -- 1.3 Gold-Catalyzed Reactions -- 1.4 Platinum-Catalyzed Reactions -- 1.5 Palladium-Catalyzed Reactions -- 1.6 Lanthanum-Catalyzed Reactions -- 1.7 Gallium-Catalyzed Reactions -- 1.8 Conclusion -- References -- 2 Intramolecular Diamination of Alkenes -- 2.1 Introduction -- 2.2 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intramolecular Vicinal Diamination of Alkenes -- 2.2.1 Palladium Catalysis -- 2.2.2 Other Metal Catalysis Using Iodine(III) Oxidants -- 2.2.3 Copper Catalysis -- 2.3 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intra-/Intermolecular Vicinal Diamination of Alkenes -- 2.3.1 Palladium Catalysis -- 2.3.2 Copper Catalysis -- 2.4 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intermolecular Vicinal Diamination of Alkenes -- 2.5 Summary and Outlook -- References -- 3 Synthesis of Heterocycles by Palladium-Catalyzed Carbonylative Reactions -- 3.1 Introduction -- 3.2 Palladium-Catalyzed Cyclocarbonylations Leading to Heterocycles -- 3.2.1 Under Oxidative Conditions -- 3.2.1.1 With Alkyne and Alkene Derivatives (Without Direct C-H Activation) -- 3.2.1.2 With Acetylenic C-H Activation -- 3.2.1.3 With Alkenylic C-H Activation -- 3.2.1.4 With Aromatic C-H Activation -- 3.2.1.5 With Aliphatic C-H Activation -- 3.2.1.6 With Diols, β-Amino Alcohols, Diamines, and Related Compounds -- 3.2.2 Under Nonoxidative Conditions -- 3.2.2.1 With Functionalized Halides -- 3.2.2.2 With Halides Together With Nucleophilic Partners -- 3.2.2.3 With Halides Together With Electrophilic Partners. , 3.2.2.4 With Halides Together With Alkenes and Imines -- 3.2.2.5 With Halides Together With Alkynes and Arynes -- 3.2.2.6 With Other Substrates -- 3.3 Palladium-Catalyzed Carbonylation Processes Leading to Heterocycles Without Incorporation of CO into the Cycle -- 3.3.1 Under Oxidative Conditions -- 3.3.1.1 Through Carbonylative Carbocyclization -- 3.3.1.2 Through Heterocyclization-Alkoxycarbonylation -- 3.3.1.3 Through Heterocyclization-Carbonylation-Cyclization Coupling -- 3.3.1.4 Through Monocarbonylation of Terminal Alkynes Followed by Intramolecular Conjugate Addition -- 3.3.2 Under Nonoxidative Conditions -- 3.3.2.1 With Halides -- 3.3.2.2 With Imine Derivatives -- 3.3.2.3 With Functionalized Alkynes -- 3.4 Conclusions and Perspectives -- References -- 4 Synthesis of Heterocyclic Compounds Based on Transition-Metal-Catalyzed Carbene Coupling Reactions -- 4.1 Introduction -- 4.2 Cyclization Prior to Metal Carbene Formation -- 4.3 Cyclization Through Other Carbene Precursors -- 4.4 Cyclization Through Reductive Elimination -- 4.5 Cyclization Through Nucleophilic Displacement -- 4.6 Synthesis of Heterocycles Through Condensation or Addition -- 4.7 Tandem Catalysis Process -- 4.8 Conclusion and Outlook -- References -- 5 Synthesis of Heterocycles With Iron Salts as Sustainable Metal Catalysts -- 5.1 Introduction -- 5.2 σ-Bond Activation -- 5.2.1 σ-Activation Via Insertion of the Molecule into the Coordination Sphere of the Metal -- 5.2.2 σ-Bond Activation Via Complexation With Functional Groups -- 5.2.2.1 Hydroxy Activation -- 5.2.2.2 Amine Activation -- 5.2.2.3 Diselenide Activation -- 5.2.2.3.1 Benzo[b]furan-Fused Selenophenes -- 5.2.2.4 Ester Activation -- 5.3 π-Bond Activation -- 5.4 Radical Reactions -- 5.5 Conclusions and Outlook -- Acknowledgments -- References -- 6 Allene Aziridination as a Tool for the Synthesis of Complex Amines. , 6.1 Introduction -- 6.2 Heterocycle Formation Via Nontransition Metal-Catalyzed Allene Amination -- 6.3 Transition Metal-Catalyzed Allene Amination Not Involving Methyleneaziridine Intermediates -- 6.4 Transition Metal-Catalyzed Allene Aziridination to Methyleneaziridines -- 6.4.1 General Features of Alkylidene or Methyleneaziridines -- 6.4.2 Intramolecular Allene Aziridination Using Carbamate Precursors -- 6.4.3 Intramolecular Allene Aziridination Using Sulfamate Precursors -- 6.4.4 Intermolecular Allene Aziridinations -- 6.5 Strategies for the Synthesis of Heterocycles Via Allene Aziridination -- 6.5.1 Nucleophilic Ring-Opening of Methyleneaziridines -- 6.5.2 Methyleneaziridine Oxidation and Rearrangement Strategies -- 6.5.3 Formation of 2-Amidoallyl Cation Intermediates -- 6.5.4 Other Reactivity of Bicyclic Methyleneaziridines -- 6.5.4.1 Synthesis of Strained Cycloalkynes -- 6.5.4.2 Synthesis of Highly Substituted Methyleneazetidines and Azetidines -- 6.6 Synthetic Applications of Allene Aziridination to Complex Molecule Synthesis -- 6.6.1 Aminosugars -- 6.6.2 Total Synthesis of (±)-Detoxinine Methyl Ester and Its Stereoisomers -- 6.6.3 Fluorinated Pyrrolidines and Unnatural Amino Acids -- 6.6.4 Aminocyclopentitol Core of Jogyamycin -- 6.7 Conclusion and Outlook -- References -- 7 Zinc-Mediated Synthesis of Heterocycles -- 7.1 Introduction -- 7.2 Zinc-Catalyzed Synthesis of Heterocycles Through Addition Reactions to Alkenes and Alkynes -- 7.2.1 Syntheses of N-Heterocycles by Zinc-Catalyzed Hydroamination Reactions -- 7.2.2 Syntheses of O-Heterocycles by Zinc-Catalyzed Hydroalkoxylation and Related Reactions -- 7.2.3 Syntheses of Heterocycles Involving Zinc-Catalyzed Addition Reactions of C-Nucleophiles to Alkynes -- 7.2.4 Other Zinc-Catalyzed Syntheses of Heterocycles Involving Transformations with Unsaturated Substrates. , 7.3 Zinc-Catalyzed Synthesis of Heterocycles Through Formal Cycloaddition Reactions -- 7.3.1 Zinc-Catalyzed Formal [4+2]-Cycloadditions -- 7.3.2 Zinc-Promoted [3+2]-Cycloadditions -- 7.3.3 Other Zinc-Promoted Cycloadditions -- 7.4 Zinc-Promoted Synthesis of Heterocycles through Condensation-Cyclization Reaction Sequences -- 7.5 Zinc-Promoted Synthesis of Heterocycles Through Michael Addition-Cyclization Reaction Sequences -- 7.6 Zinc-Catalyzed Synthesis of Cyclic Carbonate Derivatives Using CO2 -- 7.7 Summary and Outlook -- References -- 8 Controlling Selectivities in Palladium-Catalyzed Cyclization Reactions Leading to Heterocycles: From Ambiphilic Reactions... -- 8.1 Introduction -- 8.2 Chemoselectivity Control in Intramolecular Pd-Catalyzed Reactions of Amino-Tethered Aryl Halides and Ketones -- 8.3 Chemoselectivity Control in Intramolecular Pd-Catalyzed Reactions of Amino-Tethered Aryl Halides and Aldehydes -- 8.4 Chemoselectivity Control in Intramolecular Pd-Catalyzed Reactions of β-(2-Iodoanilino)esters and β-(2-Iodoanilino)carbo... -- 8.5 Catalyst-Controlled Selective Intramolecular C-H Insertion of α-Diazo Carbonyl Derivatives -- 8.6 Summary and Conclusions -- References -- Index -- Back Cover.

Language: English