UID:
almahu_9948025463902882
Format:
1 online resource (427 p.)
ISBN:
1-281-03428-2
,
9786611034283
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0-08-053526-7
Series Statement:
Comprehensive chemical kinetics ; v. 38
Content:
This book addresses primarily the chemist and engineer in industrial research and process development, where competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such scale-up should be based on ""fundamental"" kinetics, that is, mathematics that reflect the elementary steps of which the reactions consist. The book forges fundamental kinetics into a practical tool by presenting new effective methods for elucidation of mechanisms and reduction of mathematical complexity without unacceptable sacrifice in accuracy.
Note:
Description based upon print version of record.
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Front Cover; KINETICS OF HOMOGENEOUS MULTISTEP REACTIONS; Copyright Page; Contents; Preface; Introduction; References; Chapter 1. Concepts, definitions, conventions, and notation; 1.1. Classification of reactions; 1.2. Steps, pathways, networks, and cycles; 1.3. Rates; 1.4. Rate equations and activation energies; 1.5. Orders, molecularities, and ranks; 1.6. Conversion, yield, and selectivity; Summary; References; Chapter 2. Fundamentals; 2.1. Statistical basis: molecularities and reaction orders; 2.2. Nonideality; 2.3. Temperature dependence
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2.4. Compilation of rate equations of multistep reactions2.5. Consistency criteria; Summary; References; Chapter 3. Determination of rates, orders, and rate coefficients; 3.1. Research reactors; 3.2. Analytical support; 3.3. Reaction orders and apparent rate coefficients; 3.4. Numerical work-up, error recognition, and reliability; Summary; References; Chapter 4. Tools for reduction of complexity; 4.1. Rate-controlling steps; 4.2. Quasi-equilibrium steps; 4.3. Quasi-stationary states: the Bodenstein approximation
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4.4. Relative abundance of species in catalysis and polymerization and long-chain approximationSummary; References; Chapter 5. Elementary step combinations; 5.1. Reversible reactions; 5.2. Parallel steps; 5.3. Coupled parallel steps; 5.4. Sequential steps; 5.5. Competing steps; 5.6. Reactions with fast pre-dissociation; 5.7. General solution for first-order networks; Summary; References; Chapter 6. Practical mathematics of multistep reactions; 6.1. Simple and non-simple pathways and networks; 6.2. Pseudo-first order rate coefficients; 6.3. General formula for simple pathways
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6.4. Simple networks6.5. Non-simple pathways and networks; Summary; References; Chapter 7. Network elucidation; 7.1. Order and rank; 7.2. ""One plus"" rate equations; 7.3. Relationships between network properties and kinetic behavior; 7.4. Other criteria and guidelines; 7.5. Auxiliary techniques; Summary; References; Chapter 8. Homogeneous catalysis; 8.1. Single-species catalysis; 8.2. Complex catalysis; 8.3. Classical models of enzyme kinetics; 8.4. General formula for single catalytic cycles: Christiansen mathematics; 8.5. Reduction of complexity
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8.6. Relationships between pathway properties and kinetic behavior8.7. Cycles with external reactions; 8.8. Multiple cycles; 8.9. Self-accelerating reactions (autocatalysis); 8.10. Analogies to heterogeneous catalysis; Summary; References; Chapter 9. Chain reactions; 9.1. General properties; 9.2. Initiation; 9.3. Reactions with two chain carriers: the hydrogen-bromide reaction; 9.4. Identification of relevant steps; 9.5. Transmission of reactivity: indirect initiation, chain transfer; 9.6. Reactions with more than two free radicals; 9.7. Inhibition and induction periods; Summary; References
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Chapter 10. Polymerization
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English
Additional Edition:
ISBN 0-444-82606-8
Language:
English
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