Format:
7
,
Illustrationen, Diagramme
ISSN:
1528-7505
Content:
The epitaxial growth of Ga2O3 and In2O3 on (0001)-oriented Al2O3 by plasma-assisted molecular beam epitaxy is investigated. The synthesis of both materials underlies similar growth kinetics, with the formation of volatile suboxides limiting their growth in the metal-rich regime. Quantitative analysis of β-Ga2O3 and c-In2O3 growth kinetics has been performed on appropriate buffer layers mimicking homoepitaxial growth conditions. In particular, we investigate the influence of the amount of supplied atomic oxygen on the growth kinetics of β-Ga2O3. Considering the heteroepitaxial growth on bare (0001) Al2O3, we found that the observed nucleation window is much more limited than the expected growth window derived from homoepitaxial growth conditions. For Ga2O3 this was studied in detail and the upper limit of the nucleation window was determined in terms of the gallium to oxygen ratio on the growth surface and the growth temperature. Outside the nucleation window, we report that three monolayers α-(Al0.75±0.04Ga0.25∓0.04)2O3 formed in the initial stage of growth passivate the surface with respect to further β-Ga2O3 nucleation. We attribute the formation of this layer to the intermixing of a Ga-rich adlayer and Al atoms from the substrate until the solubility limit in the α-phase is reached. The observation is accompanied by a specific RHEED pattern with satellite reflexes assigned to a surface reconstruction in the metal-rich growth regime.
Note:
Gesehen am 23.03.2024
,
Publication Date: 23 May 2023
In:
Crystal growth & design, Washington, DC : ACS Publ., 2001, 23(2023), 6, Seite 4435-4441, 1528-7505
In:
volume:23
In:
year:2023
In:
number:6
In:
pages:4435-4441
In:
extent:7
Language:
English
DOI:
10.1021/acs.cgd.3c00193
Author information:
Rosenauer, Andreas 1964-
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