UID:
almahu_9948025360602882
Format:
1 online resource (420 p.)
ISBN:
1-281-98447-7
,
9786611984472
,
0-08-086819-3
Series Statement:
Comprehensive chemical kinetics ; v. 25
Content:
Diffusion-Limited Reactions
Note:
Description based upon print version of record.
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Front Cover; Diffusion-limited Reactions, Volume 25; Copyright Page; Contents; Preface; Chapter 1. Introduction; Chapter 2. Diffusion-controlled reactions in solution; 1. Introduction; 2. Evidence that some reactions are diffusion-controlled; 3. The smoluchowski theory; 4. The incorporation of chemical reaction rates into the diffusion model; 5. A comparison of Experimental results with the smoluchowski theory; 6. Complications to the dimple diffusion model; Chapter 3. Reactions between Ions in solution; 1. Theoretical considerations for Ionic reactions in solutions
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2. Experimental studies of Ionic reactions in solutionChapter 4. Long-range transfer effects and diffusion-controlled reactions; 1. General theoretical considerations; 2. The dipole-dipole interaction; 3. The exchange effect; 4. Electron tunnelling; 5. Conclusions; Chapter 5. Rotational diffusion effects; 1. Introduction; 2. Theoretical aspects of rotational relaxation; 3. Experimental studies of rotational relaxation; 4. Simultaneous rotational and translational diffusion; Chapter 6. The escape probability of an isolated pair; 1. Introduction; 2. Geminate radical recombination. Theory
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3. Experimental studies of radical and molecular recombination4. The effect of a magnetic field on radical pair recombination; Chapter 7. Geminate ion-pair recombination; 1. Introduction; 2. Theory of recombination of ion-pairs; 3. Experimental studies of geminate ion-pair recombination; 4. Spurs produced by high-energy radiation; Chapter 8. A critique of the diffusion equation and molecular pair treatments; 1. Introduction; 2. Diffusion equation analysis; 3. Molecular pair analysis; 4. Conclusions, for future work
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Chapter 9. Refinements to the diffusion equation analysis to include many-body effects1. Introduction; 2. The diffusion of an isolated pair; 3. Hydrodynamic repulsion and the diffusion equation; 4. The wilemski and fixman theory of fluorescence quenching; 5. Competitive effects in reactions; 6. The density and survival probability of radicals and ions in clusters; Chapter 10. The variational principle; 1. Introduction; 2. The lagrangian density; 3. Rate coefficients from the variational principle; 4. Diffusion on a cubic lattice of sinks; 5. Further estimates of the rate coefficient
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6. ConclusionsChapter 11. Phenomenological brownian motion; 1. Introduction; 2. The velocity autocorrelation function; 3 . From the Langevin equation to the diffusion equation; 4. The generalised langevin equation and chemical reactions; 5. Computer simulations; Chapter 12. The kinetic theory applied to chemical reactions in solutions; 1. Introduction; 2. The kinetic theory of fluids; 3. The rate of a chemical reaction from the kinetic theory of fluids; 4. Extensions to the Kinetic Theory; Appendix a second-order partial differential equations and Green's functions; 1. Dirac delta functions
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2. Inhomogeneous second-order (partial) differential equations
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English
Additional Edition:
ISBN 0-444-42354-0
Language:
English
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