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  • 1
    UID:
    b3kat_BV046353443
    Format: 159 Seiten , Illustrationen, Diagramme , 24 cm
    ISBN: 2903148031
    In: 2
    Language: English
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  • 2
    UID:
    kobvindex_GFZ94171
    Format: 247 p.
    Edition: 3. ed.
    ISBN: 0632034785
    Note: MAB0014.001: PIK N 531-97-0359
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  • 3
    UID:
    almahu_9949198450402882
    Format: 468 p. , online resource.
    Edition: 1st ed. 1984.
    ISBN: 9781461326519
    Content: The continually growing contribution of transition metal chemistry to synthetic organic chemistry is, of course, widely recognized. Equally well­ known is the difficulty in keeping up-to-date with the multifarious reactions and procedures that seem to be spawned at an ever-increasing rate. These can certainly be summarized on the basis of reviews under the headings of the individual transition metals. More useful to the bench organic chemist, however, would be the opposite type of concordance based on the structural type of the desired synthetic product. This is the approach taken in the present monograph, which presents for each structural entity a conspectus of the transition metal-mediated processes that can be employed in its production. The resulting comparative survey should be a great help in devising the optimum synthetic approach for a particular goal. It is presented from an essentially practical viewpoint, with detailed direc­ tions interspersed in the Houben-Weyl style. The wide scope of the volume should certainly encourage synthetic organic chemists to utilize fully the range and versatility of these transition metal-mediated processes. This will certainly be a well-thumbed reference book! R. A. RAPHAEL Cambridge University v Preface In recent years an enormous amount of work has been done on the catalysis of organic reactions by various transition metal species and on the organic reactivity of organo-transition-metal compounds.
    Note: 1. Introduction -- 2. Formation of Carbon-Carbon Bonds -- 2.1. Formation of Carbon-Carbon Single Bonds -- 2.2. Formation of Carbon-Carbon Double Bonds -- 3. Formation of Carbocyclic Compounds -- 3.1. Introduction -- 3.2. Formation of Three-Membered Rings -- 3.3. Formation of Four-Membered Rings -- 3.4. Formation of Five-Membered Rings -- 3.5. Formation of Six-Membered Rings -- 3.6. Formation of Seven-Membered Rings -- 3.7. Formation of Eight-Membered Rings -- 3.8. Formation of Large Rings (?9) -- 4. Formation of Heterocyclic Compounds -- 4.1. Introduction -- 4.2. Nitrogen Heterocycles -- 4.3. Oxygen Heterocycles -- 4.4. Sulfur Heterocycles -- 4.5. Cyclic Compounds Containing Two Hetero Atoms -- 5. Isomerization of Alkenes -- 5.1. Introduction -- 5.2. Thermodynamic Considerations -- 5.3. Isolation of Organometallic Intermediates -- 5.4. Mechanisms of Catalytic Alkene Isomerization -- 5.5. Formation of a,?-Unsaturated Compounds -- 5.6. Formation of Conjugated Dienes -- 5.7. Migration into Conjugation with Aromatic Rings -- 5.8. Formation of Aromatic Compounds-Isoaromatization -- 6. Direct Introduction and Removal of Carbonyl Groups -- 6.1. Preliminaries -- 6.2. Preparation of Carboxylic Acids, Esters, and Related Derivatives -- 6.3. Preparation of Aldehydes -- 6.4. Preparation of Ketones -- 6.5. Preparation of Isocyanates -- 6.6. Decarbonylation of Aldehydes and Acyl Halides -- 7. Reduction -- 7.1. Introduction -- 7.2. Reduction of Triple Bonds -- 7.3. Reduction of Double Bonds (Nonaromatic) -- 7.4. Reduction of Aromatic Systems -- 7.5. Reduction of Carbonyl Groups -- 7.6. Reduction of Nitro, Nitrile, and Other Nitrogen-Containing Functional Groups -- 7.7. Asymmetric Hydrogenation -- 7.8. Hydrogenolysis -- 8. Oxidation -- 8.1. Formation of Alcohols -- 8.2. Formation of 1,2 Diols and Amino Alcohols -- 8.3. Acetoxylation -- 8.4. Epoxidation -- 8.5. Formation of Aldehydes and Ketones -- 8.6. Formation of Acids -- 8.7. Formation of Esters -- 8.8. Dehydrogenation -- 9. Preparing and Handling Transition Metal Catalysts -- 9.1. Introduction -- 9.2. Preparation of Catalysts -- 9.3. Metal Acetylacetonates -- 9.4. Arene Metal Tricarbonyls-ArM(CO)3 (M = Cr, Mo, or W) -- 9.5. Transition Metal Carbonyls -- 9.6. Recovery of Precious Metals -- 9.7. Handling Air-Sensitive Compounds -- References -- Compound Index.
    In: Springer Nature eBook
    Additional Edition: Printed edition: ISBN 9781461296539
    Additional Edition: Printed edition: ISBN 9780306413186
    Additional Edition: Printed edition: ISBN 9781461326526
    Language: English
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  • 4
    UID:
    almahu_9949198831802882
    Format: XI, 296 p. 7 illus. , online resource.
    Edition: 1st ed. 1991.
    ISBN: 9781475795769
    Content: Since the publication of our earlier book on transition metal mediated organic synthesis, * there has been a widespread increase of interest in this topic, and transition metal based methodology has become firmly established in many areas of organic chemistry. The direct, catalytic formation of organic carbonyl compounds using carbon monoxide as the source of the carbonyl group has seen exceptional progress, and this carbonylation chemistry is being used increasingly in research and on a larger scale for fine chemicals production. In view of these developments, there is a need for a modem, practi­ cally oriented book dealing with transition metal based carbonylation chemistry. The present monograph should help fulfill this need, since it is intended specifically to foster the adoption of catalytic carbonylation as a general tool in synthetic organic chemistry. It deals exclusively with reactions involving the interconversion of carbon monoxide and organic carbonyl compounds, and although the majority of the reactions discussed involve catalytic formation of carbonyl compounds, potentially valuable syntheses requiring stoichiometric quantities of transition metal are also included. In addition, a chapter is devoted to the remarkably useful reverse transformation (decarbonylation), in which an organic carbonyl group is eliminated in the form of carbon monoxide.
    Note: 1. Introduction -- 2. Reaction Mechanisms in Carbonylation Chemistry -- 3. Practical Aspects -- 4. Synthesis of Aldehydes -- 5. Synthesis of Ketones -- 6. Synthesis of Carboxylic Acids -- 7. Synthesis of Esters -- 8. Synthesis of Amides and Further Carboxylic Acid Derivatives -- 9. Synthesis of Lactones -- 10. Synthesis of Lactams and Related N-Heterocycles -- 11. Decarbonylation Reactions -- 12. Catalyst Preparations and Recovery of Precious Metals -- Appendixes -- 1. Suppliers of Transition Metal Catalysts and Reagents -- 2. Carbon Monoxide Suppliers -- 3. Gas Monitors -- 4. Suppliers of Autoclave Equipment -- References.
    In: Springer Nature eBook
    Additional Edition: Printed edition: ISBN 9781475795783
    Additional Edition: Printed edition: ISBN 9781475795776
    Additional Edition: Printed edition: ISBN 9780306437472
    Language: English
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  • 5
    UID:
    almahu_9949198700902882
    Format: XXXVI, 1058 p. , online resource.
    Edition: 1st ed. 1986.
    ISBN: 9789401704458
    Series Statement: Nato Science Series E:, Applied Sciences ; 108/109
    Content: An Advanced Study Institute on Fast Electrical and Optical Diagnostic Principles and Techniques was held at II Ciocco, Castelvecchio Pascoli, Italy, 10-24 July 1983. This publication is the Proceedings from that Institute. The Institute was attended by ninety-seven participants representing the United States, West Germany, the United Kingdom, Switzerland, Norway, the Netherlands, Italy, and France. The objective of the Institute was to provide a broad but comprehensive presentation of the various measurement and analy­ sis techniques that can be employed to investigate fast physical events, nominally in the sub-microsecond regime. This requires both an understanding of the basic principles underlying the diagnostic employed and its limitations, and a knowledge of the practical techniques available to obtain reliable and repeatable data. This Institute was thus structured to begin tutorially, followed by more practical techniques, demonstrations, and discussions. The Institute was divided into the following major sections: (1) Overview of Applications and Needs; (2) Voltage and Current Measurements; (3) Data Acquisition; (4) Grounding and Shield­ ing; (5) Fast Photography; (6) Refractive Index Measurements; (7) X-ray Diagnostics; (8) Spectroscopy; and (9) Active Opti­ cal Techniques. This Proceeding has been divided into two separate volumes. Volume 1, Current and Voltage Measurements, includes Sections (1) through (4) above; Volume 2, Optical Meas­ urements, includes Sections (5) through (9).
    Note: Overview of Applications and Needs -- Overview of Applications and Needs -- Voltage and Current Measurements -- Electro-Optical Measurement Techniques -- Electro-Optical and Magneto-Optical Studies of Cold Cathode Electron Beam Gun Discharges -- Fiber Optic Magnetic Field and Current Sensors -- An Electro-Optical Technique for Measuring High Frequency Free-Space Electric Fields -- Electromagnetic Sensors and Measurement Techniques -- Ultrafast Electrical Voltage and Current Monitors -- High Speed Electric Field and Voltage Measurements -- High Speed Magnetic Field and Current Measurements -- Nuclear Reaction Diagnostics for Intense Particle Beam Measurements -- Particle Analyzer Diagnostics for Intense Particle Beam Measurements -- Data Acquisition -- Software Correction of Measured Pulse Data -- Fiber Optic Links for Data Acquisition, Communication, and Control -- A High Speed Multi-Channel Data Recorder -- An Iterative Deconvolution Algorithm for the Reconstruction of High-Voltage Impulses Distorted by the Measuring System -- Test Methods for the Dynamic Performance of Fast Digital Recorders -- Grounding and Shielding -- Electromagnetic Topology for the Analysis and Design of Complex Electromagnetic Systems -- Basic Principles of Grounding and Shielding with Respect to Equivalent Circuits -- System Design: Practical Shielding and Grounding Techniques Based on Electromagnetic Topology -- A Systematic, Practical Approach to the Design of Shielded Enclosures for Data Acquisition and Control -- Fast Photography -- Advances in High Speed Photography: 1972-1982 -- Recent Techniques for High-Speed Photography and Low-Level Image Recording -- Laser Photographic and Cinematographic Applications to the Investigation of Transient Phenomena -- Refractive Index Measurements -- Concepts and Illustrations of Optical Probing Diagnostics for Laser-Produced Plasmas -- Sub-Nanosecond, Four-Frame, Holographic Interferometry Diagnostics -- Laser Interferometry: Streaked Shadowgraphy and Schlieren Imaging -- Moire-Schlieren, Time-Differential Interferometry, and Enhanced Sensitivity of Faraday Rotation Measurements -- Twenty-Picosecond Pulsed UV Holographic Interferometry of Laser-Induced Plasmas -- X-Ray Diagnostics -- Nondispersive X-Ray Diagnostics of Short-Lived Plasmas -- High Energy X-Ray Diagnostics of Short-Lived Plasmas -- Fiber Optics in X-Ray Diagnostics Applications -- Flash Radiography -- 3-ns Flash X-Radiography -- Spectroscopy -- Principles of Plasma Spectroscopy -- Spectroscopy of Laser-Produced Plasmas -- Active Optical Techniques -- Laser Induced Fluorescence Techniques -- Multiphoton Techniques for the Detection of Atoms -- Coherent Anti-Stokes Raman Scattering -- Thomson Scattering Diagnostic for Intense Relativistic Electron Beam Experiment -- Appendix A: Ranking of Diagnostic Techniques -- A. K. Hyder, M. F. Rose, M. Kristiansen -- Participants.
    In: Springer Nature eBook
    Additional Edition: Printed edition: ISBN 9789401704472
    Additional Edition: Printed edition: ISBN 9789401704465
    Additional Edition: Printed edition: ISBN 9789024732951
    Language: English
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