Format:
1 Online-Ressource (13 Seiten)
Content:
We present an analytical model based on the time-dependentWKB approximation to reproduce the photoionization spectra of anH2 molecule in the autoionization region.Weexplore the nondissociative channel, which is the major contribution after one-photon absorption, and we focus on the features arising in the energy differential spectra due to the interference between the direct and the autoionization pathways. These features depend on both the timescale of the electronic decay of the autoionizing state and the time evolution of the vibrational wavepacket created in this state. With full ab initio calculations and with a one-dimensional approach that only takes into account the nuclear wavepacket associated to the few relevant electronic states we compare the ground state, the autoionizing state, and the background continuum electronic states. Finally, we illustrate how these features transform from molecular-like to atomic-like by increasing the mass of the system, thus making the electronic decay time shorter than the nuclear wavepacket motion associated with the resonant state. In other words, autoionization then occurs faster than the molecular dissociation into neutrals.
Content:
Peer Reviewed
In:
New journal of physics, [London] : IOP, 17,2015,5
Language:
English
DOI:
10.1088/1367-2630/17/5/053011
URN:
urn:nbn:de:kobv:11-110-18452/25010-3
URL:
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