UID:
almafu_9959327647702883
Format:
1 online resource :
,
illustrations
ISBN:
9783527807284
,
3527807284
,
9783527807291
,
3527807292
Content:
A comprehensive resource to the development and recent progress of zwitterion-oriented cycloadditions promoted by organoamines, organophosphines, N-heterocyclic carbenes Organocatalytic Cycloadditions for Synthesis of Carbo- and Heterocycles offers a clear explanationto thedevelopment of and the information on the latest research pertaining to zwitterion-oriented cycloadditions promoted by organoamines, organophosphines, N-heterocyclic carbenes. The authors'noted experts in the field'include a comprehensive review to the investigations of the reaction mechanisms and explore the synthesis of different products from the same starting materials.' Filled with illustrative examples and designed to be accessible, the text shows how to control the chemo-, regio- and stereoselectivity and explains the further design of novel cycloaddition reactions catalyzed by organoamines and organophosphines based on zwitterion-oriented synthetic strategy. This important text: -Explains why the formation of carbo- and heterocycles is a key transformation in organic synthesis.-Offers a clear description to the development of zwitterion-oriented cycloadditions promoted by organoamines, organophosphines, N-heterocyclic carbenes, and explores the latest research -Contains the most current examples involving synthetic transformations of organocatalytic cycloadducts -Includes contributions from noted experts in the field of organic synthesis Written for organic chemists, pharmaceutical chemists, chemists in industry, graduates, and librarians, Organocatalytic Cycloadditions for Synthesis of Carbo- and Heterocyclesis is the essential guide to the topic.
Note:
Cover; Title Page; Copyright; Contents; Preface; Chapter 1 Introduction to Organocatalytic Cycloaddition Reaction; 1.1 General Introduction; 1.2 General Mechanistic Insights into Cycloadditions Catalyzed by Nucleophilic Organocatalysts; 1.2.1 Mechanisms for Common Organoamine-catalyzed Cycloaddition Reactions; 1.2.2 Mechanisms for Common Organophosphine-catalyzed Cycloaddition Reactions; 1.2.3 Cycloaddition Reaction Modes Influenced By Catalysts; References; Chapter 2 Organoamines-catalyzed Cycloadditions; 2.1 Introduction; 2.2 [2+2] Cycloadditions.
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2.3.1 Ketenes and Their Analogs Involved [3+2] Cycloadditions2.3.2 MBH Adducts Derivatives (MBHADs) Involved [3+2] Cycloadditions; 2.3.3 Other Substrates Involved [3+2] Cycloadditions; 2.4 [4+2] Cycloadditions; 2.4.1 Ketene-involved [4+2] Cycloadditions; 2.4.1.1 Ketene as Dienophile-involved [4+2] Cycloadditions; 2.4.1.2 Vinyl Ketene as Diene-Involved [4+2] Cycloadditions; 2.4.2 Allenoates Involved [4+2] Cycloadditions; 2.4.2.1 Allenoates Acting as a Two-carbon Synthon in [4+2] Cycloadditions; 2.4.2.2 Allenoate Acting as a Four-carbon Synthon in [4+2] Cycloadditions.
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2.4.3 MBHADs Involved [4+2] Cycloaddition2.5 Other Cycloaddition Reactions; 2.5.1 [2+1] Cycloadditions; 2.5.2 [3+3] Formal Cycloadditions; 2.5.3 Domino Reactions; 2.5.4 Miscellaneous Cycloaddition Reactions; 2.6 Summary; References; Chapter 3 Organophosphines-Catalyzed Cycloaddition Reactions; 3.1 Introduction; 3.2 Phosphine-catalyzed [2+2] Cycloaddition Reactions; 3.3 Phosphine-catalyzed [3+n] Cycloaddition; 3.3.1 Phosphine-catalyzed [3+2] Cycloaddition; 3.3.1.1 Phosphine-catalyzed [3+2] Cycloaddition of Allenes with Alkenes and its Asymmetric Variant.
Additional Edition:
Print version: Shi, Min. Organocatalytic Cycloadditions for Synthesis of Carbo- and Heterocycles. Weinheim, Germany : John Wiley and Sons, Inc. : Wiley-VCH, 2018 ISBN 3527342680
Additional Edition:
ISBN 9783527342686
Language:
English
Keywords:
Electronic books.
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Electronic books.
;
Electronic books.
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9783527807291
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9783527807291
URL:
https://onlinelibrary.wiley.com/doi/book/10.1002/9783527807291
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