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  • 1
    UID:
    b3kat_BV047226274
    Format: 1 Online-Ressource (x, 449 Seiten)
    ISBN: 9783030689162
    Series Statement: Topics in organometallic chemistry 68
    Additional Edition: Erscheint auch als Druck-Ausgabe ISBN 978-3-030-68915-5
    Additional Edition: Erscheint auch als Druck-Ausgabe ISBN 978-3-030-68917-9
    Additional Edition: Erscheint auch als Druck-Ausgabe ISBN 978-3-030-68918-6
    Language: English
    Subjects: Chemistry/Pharmacy
    RVK:
    RVK:
    URL: Volltext  (URL des Erstveröffentlichers)
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  • 2
    UID:
    gbv_744964539
    Format: Online-Ressource (297 p) , digital
    Edition: Springer eBook Collection. Chemistry and Materials Science
    ISBN: 9783540369660
    Series Statement: Topics in Organometallic Chemistry 6
    Content: The design of efficient syntheses of medicinal agents is one of the prime goals of the process chemist in the pharmaceutical industry. The expanding list of metal-mediated reactions has had a major impact on this endeavor over the last two decades. This volume will highlight some of the areas of organometallic chemistry that have played a particularly important role in development. The chapters are written by chemists who work in the process groups of major pharmaceutical companies and fine chemical manufacturers. Having demonstrated the power of organometallics in their processes the authors herein expand upon their experiences with examples from the literature as reported by process groups within the industry. The chapters are organized either by the application of a particular metal or reaction class. Removal of the residual metal(s) from the isolated active pharmaceutical ingredient (API) is key to the release of the material for human consumption, and hence, is reviewed here as well. This volume of Topics in Organometallic Chemistry is presented to offer a representative cross section of organometallic applications in the pharmaceutical industry as well as to give an appreciation for the creativity possible in process chemistry
    Note: G.G. Wu, M. Huang: Organolithium in Asymmetric Processes -- D.L. Hughes: Applications of Organotitanium Reagents -- K. Sumi, H. Kumobayashi: Rhodium/Ruthenium Applications -- A.J. Delmonte, E.D. Dowdy and D.J. Watson: Development of Transition Metal-Mediated Cyclopropanation Reactions -- J.F. Larrow, E.N. Jacobsen: Asymmetric Processes Catalyzed by Chiral (Salen)Metal Complexes -- S.J. Mehrman, A.F. Abdel-Magid, C.A. Maryanoff and B.P. Medaer: Non-Salen Metal-Catalyzed Asymmetric Dihydroxylation and Asymmetric Aminohydroxylation of Alkenes. Practical Applications and Recent Advances -- M. Prashad: Palladium-Catalyzed Heck Arylations in the Synthesis of Active Pharmaceutical Ingredients -- A.O. King, N. Yasuda: Palladium-Catalyzed Cross-Coupling Reactions in the Synthesis of Pharmaceuticals -- J. Kant: Stereospecific Introduction of Cephalosporin Side Chains Employing Transition Metal Complexes -- J.T. Bien, G.C. Lane and M.R. Oberholzer: Removal of Metals from Process Streams: Methodologies and Applications.
    Additional Edition: ISBN 9783540016038
    Additional Edition: Erscheint auch als Druck-Ausgabe ISBN 9783642056871
    Additional Edition: Erscheint auch als Druck-Ausgabe ISBN 9783540016038
    Additional Edition: Erscheint auch als Druck-Ausgabe ISBN 9783662144237
    Language: English
    URL: Volltext  (lizenzpflichtig)
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  • 3
    UID:
    gbv_749226730
    Format: Online-Ressource (VII, 232 p) , digital
    Edition: Springer eBook Collection. Chemistry and Materials Science
    ISBN: 9783540369677
    Series Statement: Topics in Organometallic Chemistry 7
    Content: Metal-arene p-complexes show a rich and varied chemistry. The metal adds a third dimension to the planar aromatic compounds and coordination of a metal to an arene thus not only altering the reactivity of ring-carbons and substituents but also makes possible reactions that lead to chiral non-racemic products. This book, organized in nine chapters and written by leading scientists in the field provides the reader with an up-to-date treatise on the subject organized according to reaction type and use. It covers the wide spectrum of arene activation: from the electrophilic activation of h6-bound areneï⿠by p-Lewis acid metal complex fragments, to reactions of nucleophilic h2-coordinated arene complexes. The preparation of complexes is detailed, as are the scope, limitations and challenges of reactions in contemporary p-arene metal chemistry with special attention given to asymmetric transformations. The emphasis of the book is on transformations of interest to organic synthesis and on the use of the complexes as catalysts or as chiral ligands. The book is written for academic and industrial researchers in organic, organometallic, and inorganic chemistry as well as for advanced chemistry students
    Additional Edition: ISBN 9783540016045
    Additional Edition: Erscheint auch als Druck-Ausgabe ISBN 9783662144220
    Additional Edition: Erscheint auch als Druck-Ausgabe ISBN 9783540016045
    Additional Edition: Erscheint auch als Druck-Ausgabe ISBN 9783662144213
    Language: English
    URL: Volltext  (lizenzpflichtig)
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