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  • 1
    Language: English
    In: Angewandte Chemie, 04 May 2018, Vol.130(19), pp.5511-5515
    Description: A cationic fluorescent nanogel thermometer based on thermo‐responsive N‐isopropylacrylamide and environment‐sensitive benzothiadiazole was developed with a new azo compound bearing imidazolium rings as the first cationic radical initiator. This cationic fluorescent nanogel thermometer showed an excellent ability to enter live mammalian cells in a short incubation period (10 min), a high sensitivity to temperature variations in live cells (temperature resolution of 0.02–0.84 °C in the range 20–40 °C), and remarkable non‐cytotoxicity, which permitted ordinary cell proliferation and even differentiation of primary cultured cells. auf Basis eines fluoreszierenden Nanogels, das mithilfe eines kationischen Radikalinitiators erhalten wurde, kann bei kurzer Inkubationszeit (10 min) in Lebendzellen eindringen. Es reagiert hochempfindlich auf Temperaturveränderungen (Auflösung 0.02–0.84 °C) und ist nicht zellgiftig. Diese Eigenschaften ermöglichten die Proliferation gewöhnlicher Zellen und die Differenzierung von Primärkulturzellen.
    Keywords: Fluoreszenzsonden ; Fluoreszenzspektroskopie ; Kontrastmittel ; Nanopartikel ; Sensoren
    ISSN: 0044-8249
    E-ISSN: 1521-3757
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