In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 346, No. 3-4 ( 1966-08), p. 173-180
Abstract:
Cobalt(II) salts react with excess diacetylmonoxime‐β‐pyridyl‐(2)‐ethylimine (DPÄ) forming complexes of the type [Co III (DPÄ—H) 2 ]X with X Cl, J, NCS, NO 3 , ClO 4 , atmospheric oxygen being the oxidant. Starting with Co to ligand ratios of 1:2 and 1:1, complex salts of the types [Co(DPÄ—H) 2 ] 2 [Co(NCS) 4 ] and [Co(DPÄ—H) 2 ] [CoCl 3 (C 2 H 5 OH)] · C 2 H 5 OH, respectively, are obtained. The complexing ability of DPÄ is discussed and compared with those of other oxime ligands.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v346:3/4
DOI:
10.1002/zaac.19663460309
Language:
English
Publisher:
Wiley
Publication Date:
1966
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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