In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 295, No. 3-4 ( 1958-06), p. 156-172
Kurzfassung:
The electrolysis of AgCN solved in liquid ammonia has been studied. In the case of silver anodes, the silver is completely dissolved by reaction with CN‐radicals being formed during the electrolysis. On application of indifferent anodes made of platinum or graphite and in a temperature range from −79 to −34°C, the cyanide ions are primarily discharged, too. In a secondary reaction nitrogen and NH 4 CN are formed in addition to small amounts of (CN) 2 which reacts with NH 3 yielding 2,3,5,6‐tetraimino piperazine.
Materialart:
Online-Ressource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v295:3/4
DOI:
10.1002/zaac.19582950303
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
1958
ZDB Id:
201094-X
ZDB Id:
1481139-X
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