Format:
1 Online-Ressource (xxiii, 462 Seiten)
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Illustrationen, Diagramme
ISBN:
9783527830305
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9783527830312
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9783527830329
Note:
Description based on publisher supplied metadata and other sources
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Cover -- Title Page -- Copyright -- Contents -- List of Contributors -- Preface -- General Introduction -- Part I Recent Progress on Spectroscopic Techniques -- Chapter 1 Polymer Spectroscopy - Spectroscopy from the Far‐Ultraviolet to Far‐Infrared/Terahertz and Raman Spectroscopy -- 1.1 Introduction to Polymer Spectroscopy -- 1.1.1 Outline of Polymer Spectroscopy -- 1.1.2 Brief History of Polymer Spectroscopy -- 1.2 Overview of Molecular Spectroscopy from the Far‐Ultraviolet to Far‐Infrared/Terahertz and Raman Spectroscopy in Polymer Research -- 1.2.1 IR and Raman Spectroscopy Analyses -- 1.2.2 FIR/Terahertz and Low‐Frequency Raman Spectroscopy -- 1.2.3 Near‐Infrared (NIR) Spectroscopy -- 1.2.4 SERS and TERS Spectroscopy -- 1.2.5 FUV Spectroscopy -- 1.3 Specific Examples of Molecular Spectroscopy Studies of Polymers -- 1.3.1 Infrared, Raman, and NIR Spectroscopic Evidence for the Coexistence of Hydrogen Bond Types in Poly(Acrylic Acid) -- 1.3.2 Low‐Frequency Vibrational Modes of Nylon‐6 Studied by Using IR and Raman Spectroscopies and Density Functional Theory Calculations -- 1.3.3 NIR Spectra of Linear Low‐Density Polyethylene and Their Chemometrics Analysis -- 1.3.4 Study of the Crystallization Behavior of Asymmetric PLLA/PDLA Blend by IR and Raman Spectroscopy and Raman Imaging -- 1.3.5 3D SERS Imaging Using Chemically Synthesized Highly Symmetric Nanoporous Silver Microparticles -- 1.3.6 Tip‐Enhanced Raman Scattering Spectroscopy Study of Local Interactions at the Interface of Styrene-Butadiene Rubber/Multiwalled Carbon Nanotube Nanocomposites -- 1.4 Perspectives for Polymer Spectroscopy -- References -- Chapter 2 FTIR Spectroscopy and Spectroscopic Imaging for the Analysis of Polymers and Multicomponent Polymer Systems -- 2.1 Investigation of Polymers Using FTIR Spectroscopy and Spectroscopic Imaging
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2.1.1 Investigation of Miscibility in Polymer Blends -- 2.1.2 Investigation of Intermolecular Interactions -- 2.1.2.1 Investigation of Partially Miscible PMMA-PEG Blends Using Two‐Dimensional Disrelation Mapping -- 2.1.3 Investigation of Crystallization in Polymers -- 2.1.3.1 Investigation of Solvent‐Induced Crystallization in Polymers -- 2.1.3.2 Investigation of the Crystallization Process of PHB, PLLA, and Their Blends -- 2.2 Investigation of Polymers Subjected to High‐Pressure or Supercritical CO2 Using FTIR Spectroscopy and FTIR Spectroscopic Imaging -- 2.2.1 Morphology of Polymeric Materials Under High‐Pressure or Supercritical CO2 -- 2.2.2 Investigation of Interaction in Polymers Under High‐Pressure or Supercritical CO2 -- 2.2.2.1 Investigation of the Effect of High‐Pressure CO2 on the H‐Bonding in PEG-PVP Blends -- 2.2.2.2 Investigation of the Mechanism of Interaction Between CO2 and Polymers Through the Thermodynamic Parameters Produced from In Situ ATR-FTIR Spectroscopy -- 2.2.3 Investigation of Crystallization in Polymers Under High‐Pressure or Supercritical CO2 -- 2.2.4 The Investigation of Structural Changes and Crystallization Kinetics of Polymers Exposed to High‐Pressure CO2 Through In Situ High‐Pressure FTIR and FT‐Raman Spectroscopy -- 2.2.5 Investigation of Swelling and CO2 Sorption into the Polymers Under High‐Pressure or Supercritical CO2 -- 2.3 Conclusion -- References -- Chapter 3 Interfaces in Polymer Nanocomposites Characterized by Spectroscopic Techniques -- 3.1 Introduction -- 3.2 Types of Interactions at the Interface -- 3.3 Characterization of the Interfaces -- 3.3.1 Fluorescence Spectroscopy -- 3.3.2 Solid‐State NMR Spectroscopy -- 3.3.3 Vibrational Spectroscopy -- 3.3.3.1 Infrared Spectroscopy -- 3.3.3.2 Raman Spectroscopy -- 3.4 Conclusions -- References
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Chapter 4 Far‐Infrared/Terahertz and Low‐Frequency Raman Spectroscopies in Polymers -- 4.1 Introduction -- 4.2 Intermolecular Hydrogen Bonds in the Low‐Frequency Region of PHB by QCCs -- 4.3 Several Types of Intermolecular Hydrogen Bonds in PCL -- 4.4 Stress‐Induced Crystal Transition of Polybutylene Succinate (PBS) -- 4.5 The Differences in Intermolecular Hydrogen Bonding Between PET and PBT -- 4.6 THz Imaging of Polymer Film -- 4.7 Conclusions -- References -- Chapter 5 Near‐Infrared Spectroscopy and Imaging of Polymers -- 5.1 Introduction to NIR Spectroscopy -- 5.1.1 Principles of NIR Spectroscopy -- 5.1.2 Characteristics and Advantages of NIR Spectroscopy -- 5.1.3 Analysis of NIR Spectra -- 5.2 Applications to Polymer Science and Engineering of NIR Spectroscopy -- 5.2.1 Polarized NIR Spectroscopy Studies of Molecular Orientation of Polymers -- 5.2.2 Isothermal Crystallization Kinetics of Poly(3‐hydroxybutyrate) -- 5.2.3 Crystallization of Poly(3‐hydroxybutyrate‐co‐3‐hydroxyhexanoate) During Melt Extrusion Promoted by Residual Crystals -- 5.2.3.1 Outline of Online NIR Analysis and Online NIR Monitoring of the Residual Crystal Amount at the Extruder Outlet Nozzle -- 5.2.3.2 Amount of Residual Crystals at the Extruder Outlet -- 5.2.3.3 Crystallization of Extruded Strands -- 5.2.3.4 Analysis of Extruded Strand Crystallization Using the Avrami Equation -- 5.3 NIR Imaging for Polymer Sciences -- 5.3.1 Introduction -- 5.3.2 Theory of NIR Imaging -- 5.3.2.1 Acquisition of Hypercube -- 5.3.2.2 Data Transfer and Mapping -- 5.3.2.3 Feature of NIR Imaging Devices -- 5.3.3 Applications of NIR Imaging -- 5.3.3.1 Monitoring of Crystal Evolution Combined with Chemometrics -- 5.3.3.2 Quality Evaluation Potential for Wide Area -- 5.3.3.3 Diffusion Process Monitoring -- 5.3.3.4 Degradable Process Monitoring of Biodegradable Polymer
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5.3.3.5 Rapid Evaluation of the Water Content in PLA Pellets -- 5.3.3.6 Nondestructive Detection of Degraded Polylactic Acid Moldings -- References -- Chapter 6 Far Ultraviolet Spectroscopy for Polymers -- 6.1 Introduction -- 6.2 Measurement of ATR-FUV Spectra of Polymer -- 6.3 ATR-FUV Spectra of Nylons -- 6.4 ATR-FUV Spectra of Poly(3‐hydroxybutyrate) (PHB) and Its Graphene Nanocomposites -- 6.5 ATR-FUV Study of Poly(ethylene glycol) (PEG) and Its Complex with Lithium Ion (Li+) -- 6.6 Summary -- References -- Chapter 7 Synchrotron‐Based UV Resonance Raman Spectroscopy for Polymer Characterization -- 7.1 Basic Principles of Raman and UV Resonance Raman Spectroscopy -- 7.1.1 Molecular Vibrations and Raman Effect -- 7.1.2 Resonance Raman (RR) Scattering -- 7.1.3 Fundamental Applications of UV Resonance Raman Spectroscopy -- 7.2 Synchrotron‐Based UV Resonance Raman: Basic Principles and Instrumentation -- 7.2.1 Synchrotron‐Based UVRR Setup on IUVS@Elettra -- 7.3 SR‐UVRR Characterization of Biopolymers -- 7.4 UV Resonance Raman Studies on Polymeric Hydrogels -- 7.4.1 Water Confinement in Polysaccharide Hydrogels -- 7.4.2 Phase Transition in Thermo‐Sensitive Polysaccharide Hydrogels -- 7.4.3 Water and Polymer Dynamics in pH‐Responsive Polysaccharide Hydrogels -- 7.5 Conclusions -- Acknowledgment -- References -- Chapter 8 Sum Frequency Generation Spectroscopy for Understanding the Polymer Dynamics at Buried Interfaces -- 8.1 Introduction -- 8.2 Principle -- 8.3 Examples -- 8.3.1 Nonsolvent Interface -- 8.3.1.1 Polystyrene -- 8.3.2 Solid Interface -- 8.3.2.1 Polystyrene -- 8.3.2.2 Polyisoprene -- 8.3.2.3 Poly(styrene‐co‐butadiene) Rubber -- 8.4 Conclusions -- Acknowledgements -- References -- Chapter 9 Application of Two‐Dimensional Correlation Spectroscopy (2D‐COS) in Polymer Studies -- 9.1 Introduction -- 9.2 Theory -- 9.2.1 Background
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9.2.2 Properties of 2D‐COS -- 9.3 Applications of 2D‐COS in Polymer Studies -- 9.3.1 Applications of Conventional 2D‐COS -- 9.3.1.1 Biodegradable Polymers -- 9.3.1.2 Thermo‐Responsive Polymers -- 9.3.2 2D Hetero‐Spectral Correlation Analysis -- 9.3.3 Two‐Dimensional (2D) Gradient‐Mapping Method -- 9.3.4 Chemometric Techniques Combined with 2D‐COS -- 9.3.5 Smooth Factor Analysis -- 9.3.6 Projection 2D‐COS -- 9.3.7 2D‐COS for Hyperspectral Imaging -- 9.4 Conclusions -- References -- Chapter 10 Molecular Dynamics in Polymer Science -- 10.1 Introduction -- 10.2 Historical and Theoretical Background -- 10.3 Applications -- 10.3.1 Vibrational Spectra of Hydrogen‐Bonded Polymers -- 10.3.2 Studies of Interactions Between Polymers and Water -- 10.3.3 Mechanical Properties of Polymers -- 10.3.4 Interphase Interactions -- 10.4 Summary and Perspectives -- Acknowledgment -- References -- Chapter 11 Spectroscopic Analysis of Structural Transformations Associated with Poly(lactic acid) -- 11.1 Introduction -- 11.2 Spectroscopic Tools -- 11.2.1 Vibrational Features of PLA Crystals -- 11.2.2 Analysis of Disordered PLA Chains -- 11.2.3 Description of Anisotropic PLA - Polarized Spectra -- 11.3 Simulation Studies for Both Ordered and Disordered Structures -- 11.4 Analysis of Conformational Changes in PLA During Deformation -- 11.5 Aging Behavior in PLA -- 11.6 Conclusion -- Acknowledgment -- References -- Part II Topical Polymers Studied by Spectroscopy -- Chapter 12 Probing Molecular Events in Self‐Healable Polymers -- 12.1 Introduction -- 12.2 Microphase Separation -- 12.3 Entropically Driven Self‐Healing -- 12.3.1 Free Radical and Cationic Recombination -- 12.3.2 Van der Waals Interactions -- 12.3.3 Chemical Sensing of Damage-Repair Cycle -- Acknowledgments -- References -- Chapter 13 Recent Application of Vibrational Spectroscopy to Conjugated Conducting Polymers
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13.1 Introduction
Additional Edition:
Erscheint auch als Druck-Ausgabe ISBN 978-3-527-34833-6
Language:
English
Subjects:
Chemistry/Pharmacy
Keywords:
Polymere
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Spektroskopie
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Aufsatzsammlung
DOI:
10.1002/9783527830312
Author information:
Ozaki, Yukihiro 1949-
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