In:
Synthesis, Georg Thieme Verlag KG, Vol. 50, No. 03 ( 2018-02), p. 625-643
Kurzfassung:
Several new trans-dihydronarciclasine analogues were stereoselectively synthesised by applying our feasible and efficient process developed recently. These new phenanthridone alkaloid derivatives were obtained in both racemic and optically active forms. During their enantioselective syntheses, high selectivities (up to 99% ee) were achieved by using (8S,9S)-9-amino(9-deoxy)epiquinine as an organocatalyst. The modifications, the introduction of ethoxy or methoxy groups, were made in ring A of the phenanthridone scaffold.
Materialart:
Online-Ressource
ISSN:
0039-7881
,
1437-210X
DOI:
10.1055/s-0036-1591514
Sprache:
Englisch
Verlag:
Georg Thieme Verlag KG
Publikationsdatum:
2018
ZDB Id:
204080-3
ZDB Id:
2033062-5
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