In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 58, No. 10 ( 2003-10-1), p. 1027-1029
Abstract:
The octadentate ligand [N(CH 2 CH 2 NH 2 )(CH 2 CH 2 CH 2 OH)(CH 2 CH 2 S)] 2 CH 2 , (NNOS-232) 2 CH 2 , was synthesized accidentally by the reaction of the unsymmetrically substituted tripod [N(CH 2 CH 2 NH 2 )(CH 2 CH 2 CH 2 OH)(CH 2 CH 2 SH)], NNOS-232, with dichloromethane in the presence of aluminum hydroxide. Ligand (NNOS-232) 2 CH 2 was reacted with zinc bis(perchlorate) hexahydrate to yield the complex [Zn((NNOS-232) 2 CH 2 )](ClO 4 ) 2 1 exhibiting a distorted octahedrally coordinated zinc atom in an N 4 S 2 coordination environment, as shown by an X-ray diffraction study.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-2003-1016
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2003
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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