In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 40, No. 4 ( 1985-4-1), p. 447-449
Abstract:
A tetrameric zirconocene, [Cp 2 Zr] 4 , was prepared by reducing Cp 2 ZrH 2 with red or white phosphorus, with grey arsenic or with antimony in toluene. The tetramer reacts with adequate amounts of Me 3 SiCl to give Cp 2 Zr(SiMe 3 )Cl, but with Me 3 SnCl to give [Cp 2 Zr(SnMe 3 )] 2 , Cp 2 ZrCl 2 , and Sn 2 Me 6 . Reaction with Ph 2 PCl yields Cp 2 ZrCl 2 and P 2 Ph 4 .
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1985-0401
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1985
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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