In:
Acta Crystallographica Section E Structure Reports Online, International Union of Crystallography (IUCr), Vol. 70, No. 11 ( 2014-11-01), p. 365-369
Abstract:
The title compounds, C 22 H 31 NO 2 S, (1), and C 23 H 33 NO 2 S, (2), are related protected 1,2-amino alcohols. They differ in the substituents on the benzene ring, viz. 2,6-dimethylphenyl in (1) and 2,4,6-trimethylphenyl in (2). The plane of the phenyl ring is inclined to that of the benzene ring by 28.52 (7)° in (1) and by 44.65 (19)° in (2). In the crystal of (1), N—H...O=S and C—H...O=S hydrogen bonds link molecules, forming chains along [100] , while in (2), similar hydrogen bonds link molecules into chains along [010]. The absolute structures of both compounds were determined by resonance scattering.
Type of Medium:
Online Resource
ISSN:
1600-5368
DOI:
10.1107/S1600536814022570
DOI:
10.1107/S1600536814022570/su2794sup1.cif
DOI:
10.1107/S1600536814022570/su27941sup2.hkl
DOI:
10.1107/S1600536814022570/su27942sup3.hkl
DOI:
10.1107/S1600536814022570/su27941sup4.cml
DOI:
10.1107/S1600536814022570/su27942sup5.cml
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2014
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8
Bookmarklink