In:
Angewandte Chemie, Wiley, Vol. 129, No. 27 ( 2017-06-26), p. 8047-8051
Abstract:
The synthesis, metalation, and redox properties of an acyclic bis(iminothienyl)methene L − are presented. This π‐conjugated anion displayed pronounced redox activity, undergoing facile one‐electron oxidation to the acyclic, metal‐free, neutral radical L . on reaction with FeBr 2 . In contrast, the reaction of L − with CuI formed the unique, neutral Cu 2 I 2 ( L . ) complex of a ligand‐centered radical, whereas reaction with the stronger oxidant AgBF 4 formed the metal‐free radical dication L .2+ .
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v129.27
DOI:
10.1002/ange.201703576
Language:
English
Publisher:
Wiley
Publication Date:
2017
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514305-6
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505872-7
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1479266-7
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506259-7
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