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This thesis examines the solvation of alkali metal cyclopentadienyl derivatives (Cp, CpMe, Cp*, indenyl, fluorenyl) in liquid ammonia as well as in solutions of ammonia in polar aprotic solvents. The degree of solvation has been determined by single crystal X-Ray diffraction. Liquid ammonia is a very potent solvent for organometallic compounds due the small size, aprotic character, and strong electron donating properties. The liquid window, ranging from -77°C to -33°C, is challenging to handle and therfore ammonia plays a minor role in organometallic synthesis. Ammonia dissolves a range of ...
Note:
Dissertation Georg-August-Universität Göttingen 2017
Additional Edition:
Erscheint auch als Druck-Ausgabe Michel, Reent Ammonia stabilized carbanions Göttingen, 2016
Language:
English
Keywords:
Hochschulschrift
URN:
urn:nbn:de:gbv:7-11858/00-1735-0000-002E-E321-1-8
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