Format:
Online-Ressource
ISSN:
1521-3927
Content:
(1‐Adamantyl) methyl glycidyl ether (AdaGE) is introduced as a versatile monomer for oxyanionic polymerization, enabling controlled incorporation of adamantyl moieties in aliphatic polyethers. Via copolymerization with ethoxyethyl glycidyl ether (EEGE) and subsequent cleavage of the acetal protection groups of EEGE, hydrophilic linear polyglycerols with an adjustable amount of pendant adamantyl moieties are obtained. The adamantyl unit permits control over thermal properties and solubility profile of these polymers (LCST). Additionally, AdaGE is utilized as a termination agent in carbanionic polymerization, affording adamantyl‐terminated polymers. Using these structures as macroinitiators for the polymerization of ethylene oxide affords amphiphilic, in‐chain adamantyl‐functionalized block copolymers.
In:
volume:35
In:
number:11
In:
year:2014
In:
pages:1075-1080
In:
extent:6
In:
Macromolecular rapid communications, Weinheim : Wiley-VCH, 1980-, 35, Heft 11 (2014), 1075-1080 (gesamt 6), 1521-3927
Language:
English
DOI:
10.1002/marc.201400017
URN:
urn:nbn:de:101:1-2023011113143512464280
URL:
https://doi.org/10.1002/marc.201400017
URL:
https://nbn-resolving.org/urn:nbn:de:101:1-2023011113143512464280
URL:
https://d-nb.info/1277776032/34
URL:
https://doi.org/10.1002/marc.201400017
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