Abstract
Deuterofullerites C60Dx have been studied by 2H and 13C NMR. These fullerites have two types of carbon–deuterium bonds: C–D terminal bonds, characterized by the quadrupole coupling constant (QCC) of 171 kHz, and –C ··· D ··· C– bridging bonds with a QCC of 56 kHz. The latter is responsible for the rigid lattice found in these fullerites, which is untypical of fullerenes.
Similar content being viewed by others
References
A. Hirch (Ed.): Chemistry of Fullerenes (Thieme, Stuttgart 1994) Chapt. 5, pp. 117–135
N.F. Goldschleger, A.P. Moravskii: Usp. Khim 66, 353 (1997)
B.P. Tarasov, V.N. Fokin, A.P. Moravsky, Y.M. Shulga, V.A. Yartys: J. Alloys Compd. 253–254, 25 (1997)
E.L. Brosa, J. Davey, F.H. Garson, S. Gooesfeld: J. Mater. Res. 14, 2136 (1999)
Y.M. Shulga, V.M. Martynenko, B.P. Tarasov, V.N. Fokin, N.V. Chapysheva: Izv. Akad. Nauk, Ser. Khim. 1, 93 (2002)
Y.M. Shulga, V.M. Martynenko, B.P. Tarasov, V.N. Fokin, V.I. Rubtsov, N.Yu. Shulga, G.A. Krasochka, N.V. Chapysheva, V.V. Shevchenko, D.V. Schur: Phys. Solid State 44, 545 (2002)
Y.M. Shulga, A.S. Lobach, Y.G. Morozov, V.N. Spector, A.A. Ovchinnikov: Zh. Fiz. Khim. 72, 115 (1998)
V.E. Antonov, I.O. Bashkin, S.S. Khasanov, A.P.Moravsky, Y.G. Morozov, Y.M. Shulga, Y.A. Ossipiyan, E.G. Ponyatovsky: J. Alloys Compd. 330–332, 365 (2002)
Y.M. Shulga, B.P. Tarasov: JETP Lett. 68, 253 (1998)
Y.M. Shulga, B.P. Tarasov, V.M. Fokin, N.Y. Shulga, V.N. Vasilets: Fiz. Tverd. Tela 41, 1520 (1999)
K. Shigematsu, K. Abe, M. Mitani, K. Tanaka: Fullerene Sci.Technol. 1, 309 (1993)
A.S. Lobach, Y.M. Shulga, O.S. Roshchupkina, A.I. Rebrov, A.A. Perov, Y.G. Morozov, V.N. Spector, A.A. Ovchinnikov: Fullerene Sci.Technol. 6, 375 (1998)
J. Nossal, R.K. Saini, A.K. Sadana, H.F. Bettinger, L.B. Alemany, G.E. Scuseria, W.E. Billups, M. Saunders, A. Khong, R. Weisemann: J. Am. Chem. Soc. 123, 8482 (2001)
P.L. Olympia, I.Y. Wei, B.M. Fung: J. Chem. Phys. 51, 1610 (1969)
C.I. Ratchiffe: J. Phys. Chem. 91, 6464 (1987)
L. Mayas, M. Plato, C.J. Winscom, K. Mobius: Mol. Phys. 36, 753 (1978)
D.E. Izotov, V.P. Tarasov: J. Phys. Chem. B 106, 5335 (2002)
V.P. Tarasov, Yu.B. Muravlev, D.E. Izotov: Phys. Rev. B 66, 033407 (2002)
Author information
Authors and Affiliations
Corresponding author
Additional information
PACS
81.05.Tp; 82.56.Fk; 61.48.+c; 61.18.Fs; 61.10.Nz
Rights and permissions
About this article
Cite this article
Tarasov, V., Muravlev, Y., Fokin, V. et al. 2H and 13C NMR investigation of deuterofullerites C60Dx . Appl. Phys. A 78, 1001–1003 (2004). https://doi.org/10.1007/s00339-003-2421-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-003-2421-0