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2H and 13C NMR investigation of deuterofullerites C60Dx

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Abstract

Deuterofullerites C60Dx have been studied by 2H and 13C NMR. These fullerites have two types of carbon–deuterium bonds: C–D terminal bonds, characterized by the quadrupole coupling constant (QCC) of 171 kHz, and –C ··· D ··· C– bridging bonds with a QCC of 56 kHz. The latter is responsible for the rigid lattice found in these fullerites, which is untypical of fullerenes.

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Correspondence to Y.M. Shulga.

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PACS

81.05.Tp; 82.56.Fk; 61.48.+c; 61.18.Fs; 61.10.Nz

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Tarasov, V., Muravlev, Y., Fokin, V. et al. 2H and 13C NMR investigation of deuterofullerites C60Dx . Appl. Phys. A 78, 1001–1003 (2004). https://doi.org/10.1007/s00339-003-2421-0

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  • DOI: https://doi.org/10.1007/s00339-003-2421-0

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