Abstract
Formaldehyde (HCHO) is a naturally occurring compound found in ambient air which can induce cancer and sick-building syndrome. It plays an important role in the formation of OH radicals, which are connected to the formation of various airborne chemicals. Herein, we present a simple modeling for the simulation of diurnal variations in the HCHO concentration of ambient air. This was achieved using data collected during different seasons from November 2015 to March 2017 at a suburban location in Toyama City (Japan), where non-methane hydrocarbon (NMHC) levels were low at sub carbon ppm (ppmC) order. The modeling was based on the assumption that photochemical reactions of methane were the major factor of secondary HCHO formation. The model took into account the production and decomposition of HCHO by photochemical reactions as well as its loss due to other reactions such as dry deposition. Accordingly, the model’s equation contained terms for solar radiation, temperature, and methane concentration. The results predicted using the model showed good agreement with the experimental data observed on fine days, i.e., except rainy, foggy, and heavily cloudy days. The relationships between HCHO concentration and solar radiation/temperature on different days as well as the seasonal variation of HCHO concentration were also interpreted by the proposed model. This study contributes to the evaluation of the pollution levels of formaldehyde. Moreover, the model may be used to demonstrate the impact of increasing methane levels, with regard to global warming and the background levels of HCHO in the atmosphere.
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References
Atkinson R (2000) Atmospheric chemistry of VOCs and NOx. Atmos Environ 34:2063–2101. https://doi.org/10.1016/S1352-2310(99)00460-4
Atkinson R, Baulch DL, Cox RA, Crowley JN, Hampson RF, Hynes RG, Jenkin ME, Rossi MJ, Troe J (2006) Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species. Atmos Chem Phys 6:3625–4055. https://doi.org/10.5194/acp-6-3625-2006
Atmospheric Environmental Regional Observation System: AEROS (n.d.) http://soramame.taiki.go.jp/
Bianchi F, Barmet P, Stirnweis L, Haddad IE, Platt SM, Saurer M, Lötscher C, Siegwolf R, Bigi A, Hoyle CR, DeCarlo PF, Slowik JG, Prévôt ASH, Baltensperger U, Dommen J (2016) Contribution of methane to aerosol carbon mass. Atmos Environ 141:41–47. https://doi.org/10.1016/j.atmosenv.2016.06.036
Chatfield RB, Ren X, Brune W, Schwab J, College Q, PMTACS Measurement Teams (2010) Controls on urban ozone production rate as indicated by formaldehyde oxidation rate and nitric oxide. Atmos Environ 44:5395–5406. https://doi.org/10.1016/j.atmosenv.2010.08.056
Choi W, Faloona IC, Bouvier-Brown NC, McKay M, Goldstein AH, Mao J, Brune WH, LaFranchi BW, Cohen RC, Wolfe GM, Thornton JA, Sonnenfroh DM, Millet DB (2010) Observations of elevated formaldehyde over a forest canopy suggest missing sources from rapid oxidation of arboreal hydrocarbons. Atmos Chem Phys 10:8761–8781. https://doi.org/10.5194/acp-10-8761-2010
Corrêa SM, Arbilla G, Martins EM, Quitério SL, Guimarães CS, Gatti LV (2010) Five years of formaldehyde and acetaldehyde monitoring in the Rio de Janeiro downtown area – Brazil. Atmos Environ 44:2302–2308. https://doi.org/10.1016/j.atmosenv.2010.03.043
Curci G, Palmer PI, Kurosu TP, Chance K, Visconti G (2010) Estimating European volatile organic compound emissions using satellite observations of formaldehyde from the Ozone Monitoring Instrument. Atmos Chem Phys 10:11501–11517. https://doi.org/10.5194/acp-10-11501-2010
Dasgupta PK, Li J, Zhang G, Luke WT, McClenny WA, Stutz J, Fried A (2005) Summertime Ambient Formaldehyde in Five U.S. Metropolitan Areas: Nashville, Atlanta, Houston, Philadelphia, and Tampa. Environ Sci Technol 39:4767–4783. https://doi.org/10.1021/es048327d
Dutta C, Chatterjee A, Jana TK, Mukherjee AK, Sen S (2010) Contribution from the primary and secondary sources to the atmospheric formaldehyde in Kolkata, India. Sci Total Environ 408:4744–4748. https://doi.org/10.1016/j.scitotenv.2010.01.031
Frost GJ, Fried A, Lee YN, Wert B, Henry B, Drummond JR, Evans MJ, Fehsenfeld FC, Goldan PD, Holloway JD, Hubler G, Jakoubek R, Jobson BT, Knapp K, Kuster WC, Roberts J, Rudolph J, Ryerson TB, Stohl A, Stroud C, Sueper DT, Trainer M, Williams J (2002) Comparisons of box model calculations and measurements of formaldehyde from the 1997 North Atlantic regional experiment. J Geophys Res 107:ACH 3-1-3-12. https://doi.org/10.1029/2001JD000896
Gamo M, Oka T, Nakanishi J (2003) Ranking the risks of 12 major environmental pollutants that occur in Japan. Chemosphere 53:277–284. https://doi.org/10.1016/S0045-6535(03)00053-5
Garcia AR, Volkamer R, Molina LT, Molina MJ, Samuelson J, Mellqvist J, Galle B, Herndon SC, Kolb CE (2006) Separation of emitted and photochemical formaldehyde in Mexico City using a statistical analysis and a new pair of gas-phase tracers. Atmos Chem Phys 6:4545–4557. https://doi.org/10.5194/acp-6-4545-2006
Guven BB, Olaguer EP (2011) Ambient formaldehyde source attribution in Houston during TexAQS II and TRAMP. Atmos Environ 45:4272–4280. https://doi.org/10.1016/j.atmosenv.2011.04.079
Heikes B, Snow J, Egli P, O’Sullivan D, Crawford J, Olson J, Chen G, Davis D, Blake N, Blake D (2001) Formaldehyde over the central Pacific during PEM-Tropics B. J Geophys Res 106:32717–32731. https://doi.org/10.1029/2001JD900012
Ishii K, Matsumoto Y, Ito M, Ueno H, Uchida Y, Saito S, Hoshi J, Nagashima Y, Kato S, Kajii Y (2014) Source attribution of high concentration peak events of formaldehyde in the central Tokyo metropolitan area. J Jpn Soc Atmos Environ 49:252–265. https://doi.org/10.11298/taiki.49.252
Japan Meteorological Agency (n.d.) http://www.jma.go.jp/jma/indexe.html
Kesselmeier J, Kuhn U, Wolf A, Andreae MO, Ciccioli P, Brancaleoni E, Frattoni M, Guenther A, Greenberg J, Vasconcellos PDC, Oliva T, Tavares T, Artaxo P (2000) Atmospheric volatile organic compounds (VOC) at a remote tropical forest site in central Amazonia. Atmos Environ 34:4063–4072. https://doi.org/10.1016/S1352-2310(00)00186-2
Khwaja HA, Narang A (2008) Carbonyls and non-methane hydrocarbons at a rural mountain site in northeastern United States. Chemosphere 71:2030–2043. https://doi.org/10.1016/j.chemosphere.2008.01.042
Levy H II (1971) Normal atmosphere: Large radical and formaldehyde concentrations predicted. Science 173:141–143. https://doi.org/10.1126/science.173.3992.141
Lowe DC, Schmidt U (1983) Formaldehyde (HCHO) measurements in the nonurban atmosphere. J Geophys Res 88:10844–10858. https://doi.org/10.1029/JC088iC15p10844
Lui KH, Ho SSH, Louie PKK, Chan CS, Lee SC, Hu D, Chan PW, Lee JCW, Ho KF (2017) Seasonal behavior of carbonyls and source characterization of formaldehyde (HCHO) in ambient air. Atmos Environ 152:51–60. https://doi.org/10.1016/j.atmosenv.2016.12.004
Marvin MR, Wolfe GM, Salawitch RJ, Canty TP, Roberts SJ, Travis KR, Aikin KC, Gouw JA, Graus M, Hanisco TF, Holloway JS, Hubler G, Kaiser J, Keutsch FN, Peischl J, Pollack IB, Roberts JM, Ryerson TB, Veres PR, Warneke C (2017) Impact of evolving isoprene mechanisms on simulated formaldehyde: an inter-comparison supported by in situ observations from SENEX. Atmos Environ 164:325–336. https://doi.org/10.1016/j.atmosenv.2017.05.049
Ministry of the Environment Government of Japan (2015) http://www.env.go.jp/air/osen/monitoring/mon_h27/data.html
Naya M, Nakanishi J (2005) Risk assessment of formaldehyde for the general population in Japan. Regul Toxicol Pharmacol 43:232–248. https://doi.org/10.1016/j.yrtph.2005.08.002
Odabasi M, Seyfioglu R (2005) Phase partitioning of atmospheric formaldehyde in a suburban atmosphere. Atmos Environ 39:5149–5156. https://doi.org/10.1016/j.atmosenv.2005.05.006
Pang X, Mu Y, Zhang Y, Lee X, Yuan J (2009) Contribution of isoprene to formaldehyde and ozone formation based on its oxidation products measurement in Beijing, China. Atmos Environ 43:2142–2147. https://doi.org/10.1016/j.atmosenv.2009.01.022
Parrish DD, Ryerson TB, Mellqvist J, Johansson J, Fried A, Richter D, Walega JG, Washenfelder RA, Gouw JA, Peischl J, Aikin KC, McKeen SA, Frost GJ, Fehsenfeld FC, Herndon SC (2012) Primary and secondary sources of formaldehyde in urban atmospheres: Houston Texas region. Atmos Chem Phys 12:3273–3288. https://doi.org/10.5194/acp-12-3273-2012
Possanzini M, Palo VD, Cecinato A (2002) Sources and photodecomposition of formaldehyde and acetaldehyde in Rome ambient air. Atmos Environ 36:3195–3201. https://doi.org/10.1016/S1352-2310(02)00192-9
Satsumabayashi H, Kurita H, Chang YS, Carmichael GR, Ueda H (1995) Photochemical formations of lower aldehydes and lower fatty acids under long-range transport in central Japan. Atmos Environ 29:255–266. https://doi.org/10.1016/1352-2310(94)00231-9
Singh H, Chen Y, Staudt A, Jacob D, Blake D, Heikes B, Snow J (2001) Evidence from the Pacific troposphere for large global sources of oxygenated organic compounds. Nature 410:1078–1081. https://doi.org/10.1038/35074067
Smidt S, Bauer H, Pogodina O, Puxbaum H (2005) Concentrations of ethene and formaldehyde at a valley and a mountain top site in the Austrian Alps. Atmos Environ 39:4087–4091. https://doi.org/10.1016/j.atmosenv.2005.03.028
Solberg S, Dye C, Walker SE, Simpson D (2001) Long-term measurements and model calculations of formaldehyde at rural European monitoring sites. Atmos Environ 35:195–207. https://doi.org/10.1016/S1352-2310(00)00256-9
Staffelbach T, Neftel A, Stauffer B, Jacob D (1991) A record of the atmospheric methane sink from formaldehyde in polar ice cores. Nature 349:603–605. https://doi.org/10.1038/349603a0
Tago H, Kimura H, Kozawa K, Fujie K (2005) Formaldehyde concentrations in ambient air in urban and rural areas in Gunma prefecture, Japan. Water Air Soil Pollut 163:269–280. https://doi.org/10.1007/s11270-005-0720-0
Taguchi S, Murai K, Takamatsu M, Hayakawa Y, Tamizu S, Kuwata M, Katayama Y, Kuramitz H, Hata N (2012) Interpretation of the concentrations of aldehydes in rainwater over a wide area and local areas of Japan by some dominant factors. Atmos Environ 61:588–596. https://doi.org/10.1016/j.atmosenv.2012.05.012
Toda K, Hirota K, Tokunaga W, Suda D, Gushiken Y, Ohira S (2011) On-site multi monitoring of isoprene and related compounds in forest air. Bunseki Kagaku 60:489–498. https://doi.org/10.2116/bunsekikagaku.60.489
Toda K, Tokunaga W, Gushiken Y, Hirota K, Nose T, Suda D, Nagai J, Ohira SI (2012) Mobile monitoring along a street canyon and stationary forest air monitoring of formaldehyde by means of a micro-gas analysis system. J Environ Monit 14:1462–1472. https://doi.org/10.1039/c2em10935b
Vrekoussis M, Wittrock F, Richter A, Burrows JP (2010) GOME-2 observations of oxygenated VOCs: what can we learn from the ratio glyoxal to formaldehyde on a global scale? Atmos Chem Phys 10:10145–10160. https://doi.org/10.5194/acp-10-10145-2010
Xiaoyan W, Huixiang W, Shaoli W (2010) Ambient formaldehyde and its contributing factor to ozone and OH radical in a rural area. Atmos Environ 44:2074–2078. https://doi.org/10.1016/j.atmosenv.2010.03.023
Acknowledgments
We greatly thank Katayama Y., Orii T., Naya K., and Taguchi E. for helping in air sampling and meteorological measurement at the investigation sites. We also thank Kuzawa K., Toyama Prefectural Government and Kawautchi H., Sapporo City Office, for sharing the data of ambient constituents in Toyama City and Sapporo City. We would like to thank Editage (www.editage.com) for English language editing.
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This work was supported by JSPS KAKENHI (grant number JP26340002).
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ST: supervision, conceptualization, writing-original draft, writing—review and editing; MH, AS, HF, SM, MK: measurement, investigation; KS: map preparation; NH: supervision; HK: supervision, validation, writing—review and editing. All authors have read and agreed to the published version of the manuscript.
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Taguchi, S., Hagiwara, M., Shibata, A. et al. Investigation and modeling of diurnal variation in suburban ambient formaldehyde concentration. Environ Sci Pollut Res 28, 13425–13438 (2021). https://doi.org/10.1007/s11356-020-11465-w
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DOI: https://doi.org/10.1007/s11356-020-11465-w