Skip to main content
Log in

Anhydrous partial melting of an iron-rich mantle I: subsolidus phase assemblages and partial melting phase relations at 10 to 30 kbar

  • Published:
Contributions to Mineralogy and Petrology Aims and scope Submit manuscript

Abstract

Anhydrous partial melting experiments, at 10 to 30 kbar from solidus to near liquidus temperature, have been performed on an iron-rich martian mantle composition, DW. The DW subsolidus assemblage from ≤5 kbar to at least 24 kbar is a spinel lherzolite. At 25 kbar garnet is stable at the solidus along with spinel. The clinopyroxene stable on the DW solidus at and above 10 kbar is a pigeonitic clinopyroxene. Pigeonitic clinopyroxene is the first phase to melt out of the spinel lherzolite assemblage at less than 20°C above the solidus. Spinel melts out of the assemblage about 50°C above the solidus followed by a 150° to 200°C temperature interval where melts are in equilibrium with orthopyroxene and olivine. The temperature interval over which pigeonitic clinopyroxene melts out of an iron-rich spinel lherzolite assemblage is smaller than the temperature interval over which augite melts out of an iron-poor spinel lherzolite assemblage. The dominant solidus assemblage in the source regions of the Tharsis plateau, and for a large percentage of the martian mantle, is a spinel lherzolite.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • BVSP (Basaltic Volcanism Study Project) (1981) Geophysical and cosmochemical constraints on properties of mantles of the terrestrial planets. In: Basaltic volcanism on the terrestrial planets. Pergamon, New York, pp 633–699

    Google Scholar 

  • Bence AE, Albee AL (1968) Empirical correction factors for the electron microanalysis of silicates and oxides. J Geol 76:382–403

    Google Scholar 

  • Bertka CM, Holloway JR (1988) Martian mantle primary melts: an experimental study of iron-rich garnet lherzolite minimum melt composition. Proc Lunar Planet Sci Conf 18:723–739

    Google Scholar 

  • Bertka CM, Holloway JR (1994a) Anhydrous partial melting of an iron-rich mantle II: primary melt compositions at 15 kbar. Contrib Mineral Petrol 115:323–338

    Google Scholar 

  • Bertka CM, Holloway JR (1994b) Pigeonite at solidus temperatures: implications for partial melting. J Geophys Res (in press)

  • Bills BG (1989) The moments of inertia of Mars. Geophys Res Lett 16:385–388

    Google Scholar 

  • Blasius KR, Cutts JA (1976) Shield volcanism and lithospheric structure beneath the Tharsis plateau, Mars. Proc Lunar Planet Sci Conf 7:3561–3573

    Google Scholar 

  • Bohlen SR, Essene EJ, Boettcher AL (1980) Reinvestigation and application of olivine-quartz-orthopyroxene barometry. Earth Planet Sci Lett 47:1–10

    Google Scholar 

  • Boyd FR, England JL (1960) Apparatus for phase-equilibrium measurements at pressures up to 50 kilobars and temperatures up to 1750°C. J Geophys Res 65:741–748

    Google Scholar 

  • Boyd FR, England JL (1963) Effect of pressure on the melting of diopside, CaMgSi2O6, and albite, NaAlSi3O8, in the range up to 50 kilobars. J Geophys Res 68:311–323

    Google Scholar 

  • Carter JL (1970) Mineralogy and chemistry of the earth's upper mantle based on the partial fusion-partial crystallization model. Bull Geol Soc Am 81:2021–2034

    Google Scholar 

  • Carr MH (1976) The volcanoes of Mars. Sci Am 234:32–43

    Google Scholar 

  • Dreibus G, Wanke H (1985) Mars: a volatile-rich planet. Meteoritics 20:367–382

    Google Scholar 

  • Eggler DH (1978) Effect of CO2 upon partial melting of peridotite in the system Na2O−CaO−Al2O3−MgO−SiO2−CO2 to 35 kb, with an analysis of melting in a peridotite-H2O−CO2 system. Am J Sci 278:305–343

    Google Scholar 

  • Falloon TJ, Green DH, Hatton CJ, Harris KL (1988) Anhydrous partial melting of a fertile and depleted peridotite from 2 to 30 kb and application to basalt petrogenesis. J Petrol 29:1257–1282

    Google Scholar 

  • Fujii T, Scarfe CM (1985) Composition of liquids coexisting with spinel lherzolite at 10 kb and the genesis of MORBs. Contrib Mineral Petrol 90:18–28

    Google Scholar 

  • Goettel KA (1981) Density of the mantle of Mars. Geophys Res Lett 8:497–500

    Google Scholar 

  • Goettel KA (1983). Present constraints on the composition of the mantle of Mars. Carnegie Inst Washington Yearb 82:363–366

    Google Scholar 

  • Greeley R, Spudis PD (1981) Volcanism on Mars. Rev Geophys Space Phys 19:13–41

    Google Scholar 

  • Green DH (1973) Experimental melting studies on a model upper mantle composition at high pressure under water-saturated and water-undersaturated conditions. Earth Planet Sci Lett 19:37–53

    Google Scholar 

  • Green DH, Hibberson WO, Jaques AL (1979) Petrogenesis of midocean ridge basalts. In: McElhinny MW (ed) The earth: its origin, structure and evolution. Academic Press, New York, pp 265–295

    Google Scholar 

  • Gudmundsson G, Holloway JR (1988) The activity coefficient of iron in platinum at 1400°C and from 1 atm to 20 kb (abstract). EOS Trans Am Geophys Union 69:1402

    Google Scholar 

  • Gudmundsson G, Holloway JR (1993) Activity-composition relationships in the system Fe−Pt at 1300 and 1400°C and at 1 atm and 20 kbar. Am Mineral 78:178–186

    Google Scholar 

  • Hanski EJ, Smolkin VF (1989) Pechenga ferropicrites and other early proterozoic picrites in the eastern part of the Baltic Shield. Precambrian Res 45:63–82

    Google Scholar 

  • Holloway JR, Pan V, Gudmundsson G (1992) High pressure fluidabsent melting experiments in the presence of graphite: oxygen fugacity, ferric/ferrous ratio and dissolved CO2. Eur J Mineral 4:105–114

    Google Scholar 

  • Huebner JS (1971) Buffering techniques for hydroststic systems st elevated pressures. In: Ulmer GC (ed) Research techniques for high pressure and high temperature. Springer, New York, pp 123–178

    Google Scholar 

  • Jackson ED, Wright TL (1970) Xenoliths in the Honolulu volcanic series, Hawaii. J Petrol 11:405–430

    Google Scholar 

  • Jaques AL, Green DH (1980) Anhydrous melting of peridotite at 0–15 kb pressure and the genesis of tholeiitic basalts. Contrib Mineral Petrol 73:287–310

    Google Scholar 

  • Johnston DH, McGetchin TR, Toksöz MN (1974) The thermal state and internal structure of mars. J Geophys Res 79:3959–3971

    Google Scholar 

  • Johnston DH, Toksöz MN (1977) Internal structure and properties of Mars Icarus 32:73–84

    Google Scholar 

  • Kushiro I (1968) Compositions of magmas formed by partial zone melting of the earth's upper mantle. J Geophys Res 73:619–634

    Google Scholar 

  • Maaloe S, Aoki K (1977) The major element composition of the upper mantle estimated from the composition of lherzolites. Contrib Mineral Petrol 63:161–173

    Google Scholar 

  • MacGregor ID (1970) The effect of CaO, Cr2O3, Fe2O3 and Al2O3 on the stability of spinel and garnet peridotites. Phys Earth Planet Interiors 3:372–377

    Google Scholar 

  • McGetchin TR, Smyth JR (1978) The mantle of Mars: some possible geological implications of its high density. Icarus 34:512–536

    Google Scholar 

  • Millhollen GL, Irving AJ, Wyllie PJ (1974) Melting interval of peridotite with 5.7 percent water to 30 kilobars. J Geol 82:575–587

    Google Scholar 

  • Morgan JW, Anders E (1979) Chemical composition of Mars. Geochim Cosmochim Acta 43:1601–1610

    Google Scholar 

  • Mysen BO, Kushiro I (1977) Compositional variations of coexisting phases with degree of melting of peridotite in the upper mantle. Am Mineral 62:843–865

    Google Scholar 

  • Nicholls J (1977) The activities of components in natural silicate melts. In: Fraser DG (ed) Thermodynamics in geology. D Reidel, Dordrecht, Boston, pp 327–348

    Google Scholar 

  • Okal EA, Anderson DL (1978) Theoretical models for Mars and their seismic properties. Icarus 33:514–528

    Google Scholar 

  • O'Neill HStC (1981) The transition between spinel lherzolite and garnet lherzolite, and its use as a geobarometer. Contrib Mineral Petrol 77:185–194

    Google Scholar 

  • O'Neill HStC (1987) Quartz-fayalite-iron and quartz-fayalite-magnetite equilibria and the free energy of formation of fayalite (Fe2SiO4) and magnetite (Fe3O4). Am Mineral 72:67–75

    Google Scholar 

  • O'Neill HStC, Wall VJ (1987) The olivine-orthopyroxene-spinel oxygen geobarometer, the nickel precipitation curve, and the oxygen fugacity of the earth's upper mantle. J Petrol 28:1169–1191

    Google Scholar 

  • Patera ES, Holloway JR (1982) Experimental determinations of the spinel-garnet boundary in a Martian mantle composition. Proc Lunar Planet Sci Conf 14, in J Geophys Res 87:A31-A36

    Google Scholar 

  • Presnall DC, Dixon SA, Dixon JR, O'Donnell TH, Brenner NL, Schrock RL, Dycus DW (1978) Liquidus phase relations on the join diopside-forsterite-anorthite from 1 atm to 20 kb: their bearing on the generation and crystallization of basaltic magma. Contrib Mineral Petrol 66:203–220

    Google Scholar 

  • Reed SJB (1975) Electron microprobe analysis. In: Cambridge Univ. Press, Cambridge

    Google Scholar 

  • Roeder PL, Campbell IH, Jamieson HE (1979) A re-evaluation of the olivine-spinel geothermometer. Contrib Mineral Petrol 68:325–334

    Google Scholar 

  • Sack RO, Ghiorso MS (1989) Importance of considerations of mixing properties in establishing an internally consistent thermodynamic database: thermochemistry of minerals in the system Mg2SiO4−Fe2SiO4−SiO2. Contrib Mineral Petrol 102:41–68

    Google Scholar 

  • Saxena SK, Fei Y (1987) High pressure and high temperature fluid fugacities. Geochim Cosmochim Acta 51:783–791

    Google Scholar 

  • Solomon SC, Head JW (1990) Heterogeneities in the thickness of the elastic lithosphere of Mars: constraints on heat flow and internal dynamics. J Geophys Res 95:11073–11083

    Google Scholar 

  • Stolper E (1980) Predictions of mineral assemblages in planetary interiors. Proc Lunar Planet Sci Conf 11:235–250

    Google Scholar 

  • Takahashi E (1986) Melting of a dry peridotite KLB-1 up to 14 GPa: implications on the origin of peridotitic upper mantle. J Geophys Res 91:9367–9382

    Google Scholar 

  • Takahashi E, Kushiro I (1983) Melting of a dry peridotite at high pressures and basalt magma genesis. Am Mineral 68:859–879

    Google Scholar 

  • Thompson RN, Kushiro I (1972) The oxygen fugacity within graphite capsules in piston-cylinder apparatus at high pressures. Carnegie Inst Washington Yearb 71:615–616

    Google Scholar 

  • Thurber CH, Toksöz MN (1978) Martian lithospheric thickness from elastic flexure theory. Geophys Res Lett 5:977–980

    Google Scholar 

  • Wood BJ, Holloway JR (1982) Theoretical prediction of phase relationships in planetary mantles. J Geophys Res 87:A19-A30

    Google Scholar 

  • Wood CA, Ashwal LD (1981) SNC meteorites: igneous rocks from Mars? Proc Lunar Planet Sci Conf 12:1359–1375

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bertka, C.M., Holloway, J.R. Anhydrous partial melting of an iron-rich mantle I: subsolidus phase assemblages and partial melting phase relations at 10 to 30 kbar. Contr. Mineral. and Petrol. 115, 313–322 (1994). https://doi.org/10.1007/BF00310770

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00310770

Keywords

Navigation