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Studies of complex formation between macrolide antibiotics and alkali and alkali—earth metals by the voltammetry at the interface of two immiscible electrolyte solutions

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Abstract

Transfer of complexes of josamycin, spyramycin, and erythromycin with alkali and alkali-earth metals was studied using the method of voltammetry at the interface of two immiscible electrolyte solutions. Standard energies and standard transfer potentials of the formed complexes and also the values of their stability constants were determined. Stoichiometry of the complexes formed was determined. Experimentally obtained detection limits of these macrolide antibiotics in the organic phase are presented.

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Correspondence to E. V. Vladimirova.

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Original Russian Text © E.V. Vladimirova, A.A. Dunaeva, E.V. Shipulo, O.M. Petrukhin, M.V. Kostitsyna, 2011, published in Elektrokhimiya, 2011, Vol. 47, No. 3, pp. 384–391.

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Vladimirova, E.V., Dunaeva, A.A., Shipulo, E.V. et al. Studies of complex formation between macrolide antibiotics and alkali and alkali—earth metals by the voltammetry at the interface of two immiscible electrolyte solutions. Russ J Electrochem 47, 361–368 (2011). https://doi.org/10.1134/S1023193510121031

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  • DOI: https://doi.org/10.1134/S1023193510121031

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