We successfully synthesized the copper-based pnictide LiCu(2)P(2), which was reported as a superconductor with T(c) = 3.7 K before. The temperature dependence of resistivity and DC magnetization was measured on both polycrystalline and single-crystalline LiCu(2)P(2). However, our repeatable synthesizing and measurements showed no superconducting transition either in resistivity or DC magnetization above 2 K. A metallic behavior can be seen in resistivity, and a Curie-Weiss behavior was observed in DC magnetization from 2 to 300 K. We have also carried out the Hall effect and MR measurements on the sample, from which we conclude that the LiCu(2)P(2) has a single-band character. We also synthesized the polycrystalline Li(1-x)Cu(2)P(2), LiCu(2-x)P(2), and Li(1+x)Cu(2-x)P(2) with different stoichiometries, and observed no superconductivity in all the samples.