Sputtered gold and silver atoms isolated in D/sub 2/, Ne, and N/sub 2/ matrices
Journal Article
·
· Inorg. Chem.; (United States)
The spectra of sputtered gold and silver atoms isolated in D/sub 2/, Ne, and N/sub 2/ matrices are reported. An inverse relationship between Z/sub eff/ of the metal atom and ..cap alpha.., the polarizability of the matrix, has been extended to include silver atoms in D/sub 2/ and N/sub 2/ matrices. The correlation breaks down for Ne matrices apparently because the size of a substitutional site and polarizability of neon are such as to cause multiple-site occupation. Evidence for multiple-site occupation of silver in neon is presented. Intense and resolved spectra of silver dimers are also reported, and a correlation with the gas-phase spectra is made.
- Research Organization:
- Argonne National Lab., IL
- OSTI ID:
- 7084138
- Journal Information:
- Inorg. Chem.; (United States), Vol. 16:10
- Country of Publication:
- United States
- Language:
- English
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·
OSTI ID:7084138
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
GOLD
ABSORPTION SPECTRA
SILVER
ATOMS
DEUTERIUM
NEON
NITROGEN
CRYOGENIC FLUIDS
ELEMENTS
FLUIDS
HYDROGEN ISOTOPES
ISOTOPES
LIGHT NUCLEI
METALS
NONMETALS
NUCLEI
ODD-ODD NUCLEI
RARE GASES
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENTS
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
GOLD
ABSORPTION SPECTRA
SILVER
ATOMS
DEUTERIUM
NEON
NITROGEN
CRYOGENIC FLUIDS
ELEMENTS
FLUIDS
HYDROGEN ISOTOPES
ISOTOPES
LIGHT NUCLEI
METALS
NONMETALS
NUCLEI
ODD-ODD NUCLEI
RARE GASES
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENTS
400201* - Chemical & Physicochemical Properties