Niobium--dinitrogen complexes studied by infrared matrix isolation spectroscopy. [Cocondensation of Nb and N/sub 2/ at 14/sup 0/K]
Journal Article
·
· Inorg. Chem.; (United States)
Three types of infrared studies were performed on the products of condensation of Nb and N/sub 2/ in Ar matrices at 14 K: the behavior of the peaks upon annealing, the dependence of the absorbance upon the N/sub 2/:Ar ratio, and the frequencies of mixed isotope peaks. After extensive variation of experimental parameters, no explanation for the unexpected and rich spectrum could be given. The indications of the experimental results were discussed. (DDA)
- Research Organization:
- Argonne National Lab., IL
- OSTI ID:
- 7190922
- Journal Information:
- Inorg. Chem.; (United States), Vol. 15:4
- Country of Publication:
- United States
- Language:
- English
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Journal Article
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Tue Mar 01 00:00:00 EST 1988
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·
OSTI ID:7190922
Spectroscopy of transition metal species in rare gas matrices. I. Vanadium metal. II. Sulfides. III. Carbonyl complexes. IV. Dinitrogen complexes. V. Homonuclear diatomic compounds
Thesis/Dissertation
·
Wed Oct 01 00:00:00 EDT 1975
·
OSTI ID:7190922
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
NIOBIUM COMPLEXES
STRUCTURAL CHEMICAL ANALYSIS
NITROGEN 15
ISOTOPE EFFECTS
NITROGEN COMPLEXES
ANNEALING
ARGON
INFRARED SPECTRA
MATRIX ELEMENTS
COMPLEXES
ELEMENTS
HEAT TREATMENTS
ISOTOPES
LIGHT NUCLEI
NITROGEN ISOTOPES
NONMETALS
NUCLEI
ODD-EVEN NUCLEI
RARE GASES
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
NIOBIUM COMPLEXES
STRUCTURAL CHEMICAL ANALYSIS
NITROGEN 15
ISOTOPE EFFECTS
NITROGEN COMPLEXES
ANNEALING
ARGON
INFRARED SPECTRA
MATRIX ELEMENTS
COMPLEXES
ELEMENTS
HEAT TREATMENTS
ISOTOPES
LIGHT NUCLEI
NITROGEN ISOTOPES
NONMETALS
NUCLEI
ODD-EVEN NUCLEI
RARE GASES
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties