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Anodic dissolution of tin in alcohols

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Abstract

Tin(II) alcoholates Sn(OR)2 are formed upon the anodic galvanostatic dissolution of tin in alcohols in an undivided cell in the presence of minimum amounts of NaOAc as an electrolyte. Tin(II) alcoholates are easily hydrolyzed in air to form oxyhydroxide Sn3O2(OН)2 used as an anode or its composite component in lithium cells.

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Correspondence to A. N. Vereshchagin.

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Dedicated to Academician of the Russian Academy of Sciences V. M. Novotortsev on the occasion of his 70th anniversary.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0840—0843, March, 2016.

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Vereshchagin, A.N., Elinson, M.N., Goloveshkin, A.S. et al. Anodic dissolution of tin in alcohols. Russ Chem Bull 65, 840–843 (2016). https://doi.org/10.1007/s11172-016-1387-y

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  • DOI: https://doi.org/10.1007/s11172-016-1387-y

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