UID:
almafu_9960073262802883
Umfang:
1 online resource (397 p.)
Ausgabe:
1st ed.
ISBN:
1-281-07200-1
,
9786611072001
,
0-08-042798-7
,
0-08-050812-X
Serie:
Tetrahedron organic chemistry series ; v. 19
Inhalt:
From the initial observation of proton magnetic resonance in water and in paraffin, the discipline of nuclear magnetic resonance has seen unparalleled growth as an analytical method. Modern NMR spectroscopy is a highly developed, yet still evolving, subject which finds application in chemistry, biology, medicine, materials science and geology. In this book, emphasis is on the more recently developed methods of solution-state NMR applicable to chemical research, which are chosen for their wide applicability and robustness. These have, in many cases, already become established techniques in
Anmerkung:
Description based upon print version of record.
,
Cover; Contents; Foreword; Preface; Acknowledgements; Chapter 1. Introduction; 1.1. The development of high-resolution NMR; 1.2. Modern high-resolution NMR and this book; 1.3. Applying modern NMR techniques; References; Chapter 2. Introducing high-resolution NMR; 2.1. Nuclear spin and resonance; 2.2. The vector model of NMR; 2.3. Time and frequency domains; 2.4. Spin relaxation; 2.5. Mechanisms for relaxation; References; Chapter 3. Practical aspects of high-resolution NMR; 3.1. An overview of the NMR spectrometer; 3.2. Data acquisition and processing; 3.3. Preparing the sample
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3.4. Preparing the spectrometer3.5. Spectrometer calibrations; 3.6. Spectrometer performance tests; References; Chapter 4. One-dimensional techniques; 4.1. The single-pulse experiment; 4.2. Spin decoupling methods; 4.3. Spectrum editing with spin-echoes; 4.4. Sensitivity enhancement and spectrum editing; 4.5. Observing quadrupolar nuclei; References; Chapter 5. Correlations through the chemical bond I: Homonuclear shift correlation; 5.1. Introducing two-dimensional methods; 5.2. Correlation spectroscopy (COSY); 5.3. Practical aspects of 2D NMR; 5.4. Coherence and coherence transfer
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5.5. Gradient-selected spectroscopy5.6. Alternative COSY sequences; 5.7. Total correlation spectroscopy (TOCSY); 5.8. Correlating dilute spins: INADEQUATE; References; Chapter 6. Correlations through the chemical bond II: Heteronuclear shift correlation; 6.1. Introduction; 6.2. Sensitivity; 6.3. Heteronuclear single-bond correlation spectroscopy; 6.4. Heteronuclear multiple-bond correlation spectroscopy; 6.5. Traditional X-detected correlation spectroscopy; References; Chapter 7. Separating shifts and couplings: J-resolved spectroscopy; 7.1. Introduction
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7.2. Heteronuclear J-resolved spectroscopy7.3. Homonuclear J-resolved spectroscopy; 7.4. 'Indirect' homonuclear J-resolved spectroscopy; References; Chapter 8. Correlations through space: The nuclear Overhauser effect; 8.1. Introduction; 8.2. Definition of the NOE; 8.3. Steady-state NOEs; 8.4. Transient NOEs; 8.5. Rotating-frame NOEs; 8.6. Measuring steady-state NOEs: NOE difference; 8.7. Measuring transient NOEs: NOESY; 8.8. Measuring rotating-frame NOEs: ROESY; 8.9. Measuring heteronuclear NOEs; 8.10. Experimental considerations; References; Chapter 9. Experimental methods
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9.1. Composite pulses9.2. Broadband decoupling and spin-locks; 9.3. Selective excitation and shaped pulses; 9.4. Solvent suppression; 9.5. Recent methods; References; Appendix. Glossary of acronyms; Index
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English
Weitere Ausg.:
ISBN 0-08-042799-5
Sprache:
Englisch
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