Kooperativer Bibliotheksverbund

UID:

Format: 1 online resource (667 p.)

Edition: 2nd ed.

ISBN: 1-280-63557-6 , 9786610635573 , 0-08-045479-8

Content: In the ten years since the first edition appeared the renaissance in Free Radical Polymerization has continued to gain momentum. In this second revised edition, the authors critically evaluate the findings of the last decade, where necessary reinterpreting earlier work in the light of these ideas, and point to the areas where current and future research is being directed. The overall aim is to provide a framework for further extending our understanding of free radical polymerization and create a definable link between synthesis conditions and polymer structure and properties. Th

Note: Rev. ed. of: The chemistry of free radical polymerization. 1st ed. 1995. , Cover; Contents; Contents; Poly(methacrylonitrile-co- styrene); Index to Tables; Index to Figures; Preface to the First Edition; Preface to the Second Edition; Acknowledgments; INTRODUCTION; References; RADICAL REACTIONS; Introduction; Properties of Radicals; Structures of Radicals; Stabilities of Radicals; Detection of Radicals; Addition to Carbon-Carbon Double Bonds; Steric Factors; Polar Factors; Bond Strengths; Stereoelectronic Factors; Entropic Considerations; Reaction Conditions; Temperature; Solvent; Theoretical Treatments; Summary; Hydrogen Atom Transfer; Bond Dissociation Energies , Steric FactorsPolar Factors; Stereoelectronic Factors; Reaction Conditions; Abstraction TO Addition; Summary; Radical-Radical Reactions; Pathways for Combination; Pathways for Disproportionation; Combination vs Disproportionation; Statistical factors; Steric factors; Polar factors; Stereoelectronic and other factors; Reaction conditions; Summary; References; INITIATION; Introduction; The Initiation Process; Reaction with Monomer; Fragmentation; Reaction with Solvents, Additives, or Impurities; Effects of Temperature and Reaction Medium on Radical Reactivity; Reaction with Oxygen , Initiator Efficiency in Thermal InitiationPhotoinitiation; Cage Reaction and Initiator-Derived Byproducts; Primary Radical Termination; Transfer to Initiator; Initiation in Heterogeneous Polymerization; The Initiators; Azo-Compounds; Dialkyldiazenes; Thermal decomposition; Photochemical decomposition; Initiator efficiency; Transfer to initiator; Hyponitrites; Peroxides; Diacyl or diaroyl peroxides; Thermal decomposition; Photochemical decomposition; Initiator efficiency; Transfer to initiator and induced decomposition; Redox reactions; Dialkyl peroxydicarbonates; Peroxyesters , Thermal decompositionPhotochemical decomposition; Dialkyl peroxides; Alkyl hydroperoxides; Inorganic peroxides; Persulfate; Hydrogen peroxide; Multifunctional Initiators; Concerted decomposition; Non-concerted decomposition; Photochemical Initiators; Aromatic carbonyl compounds; Benzoin and related compounds; Carbonyl compound-tertiary amine systems; Sulfur compounds; Redox Initiators; Metal complex-organic halide redox systems; Ceric ion systems; Thermal Initiation; Styrene homopolymerization; Acrylate homopolymerization; Copolymerization; The Radicals; Carbon-Centered Radicals , Alkyl radicalsa-Cyanoalkyl radicals; Aryl radicals; Acyl radicals; Oxygen-Centered Radicals; Alkoxy radical; t-Butoxy radicals; Other f-alkoxy radicals; Primary and secondary alkoxy radical; Acyloxy and alkoxycarbonyloxy radicals; Benzoyloxy radicals; Alkoxycarbonyloxy radicals; Hydroxy radicals; Sulfate radical anion; Alkylperoxy radicals; Other Heteroatom-Centered Radicals; Silicon-centered radicals; Sulfur- and selenium-centered radicals; Phosphorus-centered radicals; Techniques; Kinetic Studies; Radical Trapping; Spin traps; Transition metal salts; Metal hydrides; Nitroxides , a-Methystyrene dimer , English

Additional Edition: ISBN 0-08-044288-9

Language: English

UID:

Format: XXIV, 639 S. , graph. Darst.

Edition: 2. fully rev. ed.

ISBN: 0080442889 , 0080442862 , 9780080442884 , 9780080442860

Note: Rev. ed. of: The chemistry of free radical polymerization. 1st ed. 1995 - Includes bibliographical references and index

Additional Edition: Erscheint auch als Online-Ausgabe The chemistry of radical polymerization Amsterdam : Elsevier, 2006 ISBN 9780080442884

Additional Edition: ISBN 0080442889

Additional Edition: ISBN 0080454798

Additional Edition: ISBN 9780080454795

Language: English

Subjects: Chemistry/Pharmacy

Keywords: Radikalische Polymerisation ; Radikalische Polymerisation

URL: http://www.loc.gov/catdir/enhancements/fy0625/2005055213-d.html

URL: http://www.loc.gov/catdir/enhancements/fy0625/2005055213-t.html

UID:

Format: xxvi, 639 p. : , ill.

Edition: 2nd ed.

Edition: Electronic reproduction. Ann Arbor, MI : ProQuest, 2015. Available via World Wide Web. Access may be limited to ProQuest affiliated libraries.

Note: Rev. ed. of: The chemistry of free radical polymerization. 1st ed. 1995.

Language: English

Keywords: Electronic books.

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