UID:
edocfu_9958130848902883
Format:
1 online resource (369 p.)
Edition:
2nd ed.
ISBN:
0-323-16185-5
Content:
High Resolution NMR
Note:
Description based upon print version of record.
,
Front Cover; High Resolution NMR: Theory and Chemical Applications; Copyright Page; Table of Contents; Preface to Second Edition; Preface to First Edition; Acknowledgments; Chapter 1. Introduction; 1.1 Historical; 1.2 High Resolution NMR; Chapter 2.The Theory of NMR; 2.1 Nuclear Spin and Magnetic Moment; 2.2 Classical Mechanical Description of NMR; 2.3 Quantum Mechanical Description of NMR; 2.4 Effect of the Boltzmann Distribution; 2.5 Spin-Lattice Relaxation; 2.6 Line Widths; 2.7 Saturation; 2.8 Macroscopic Magnetization; 2.9 The Bloch Equations: Nuclear Induction
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2.10 The Rotating Frame of Reference2.11 Adiabatic Passage; Ringing; Problems; Chapter 3.Instrumentation and Techniques; 3.1 Basic NMR Apparatus; 3.2 Requirements for High Resolution NMR; 3.3 Modulation and Phase Sensitive Detection; 3.4 Field/Frequency Control; 3.5 Signal/Noise and Size of Sample; 3.6 Fourier Transform Methods; 3.7 Intensity Measurements; 3.8 References; 3.9 Magnetic Susceptibility Measurements; 3.10 Frequency Calibration; 3.11 Control of Sample Temperature; 3.12 Useful Solvents; 3.13 Sampling Techniques; 3.14 Micro Techniques; Problems; Chapter 4. Chemical Shifts
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4.1 The Origin of Chemical Shifts4.2 Reference Compounds; 4.3 Chemical Shift Scales; 4.4 Magnetic Susceptibility Correction; 4.5 Empirical Correlations of Chemical Shifts; 4.6 Theory of Chemical Shifts; 4.7 Effect of Electron Density; 4.8 Magnetic Anisotropy and Chemical Shifts; 4.9 Ring Currents; 4.10 Nuclei Other Than Hydrogen; 4.11 Carbon-13; 4.12 Tabulations of Chemical Shifts and Spectra; 4.13 Empirical Estimation of Chemical Shifts; 4.14 Isotope Effects on Chemical Shifts; 4.15 Paramagnetic Species; 4.16 Lanthanide Shift Reagents; Problems
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Chapter 5. Electron-Coupled Spin-Spin Interactions5.1 Origin of Spin-Spin Coupling; 5.2 Coupling between Groups of Equivalent Nuclei; 5.3 First-Order Analysis; 5.4 Signs of Coupling Constants; 5.5 Theory of Spin-Spin Coupling; 5.6 Some Observed Coupling Constants; 5.7 Correlation of Coupling Constants with Other Physical Properties; 5.8 Tabulations of Coupling Constants; Problems; Chapter 6.The Use of NMR in Structure Elucidation; 6.1 A Systematic Approach to the Interpretation of NMR Spectra; 6.2 Some Features of Carbon-13 Spectra; 6.3 Structure Elucidation of Polymers; Problems
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Chapter 7. Analysis of Complex Spectra7.1 Notation; 7.2 Energy Levels and Transitions in an AX System; 7.3 Quantum Mechanical Formalism; 7.4 Nuclear Spin Basis Functions; 7.5 The Spin Hamiltonian; 7.6 The Two-Spin System without Coupling; 7.7 Factoring the Secular Equation; 7.8 Two Coupled Spins; 7.9 Selection Rules and Intensities; 7.10 The AB Spectrum; 7.11 Spectral Contributions from Equivalent Nuclei; 7.12 Symmetry of Wave Functions; 7.13 Summary of Rules for Calculating Spectra; 7.14 The Three-Spin System: ABC; 7.15 The A2B System; 7.16 The A3B System; Subspectral Analysis
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7.17 The ABX System
Additional Edition:
ISBN 0-12-084660-8
Language:
English
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