UID:
almafu_9958132833302883
Format:
1 online resource (560 p.)
Edition:
3rd ed.
ISBN:
0-08-091740-2
Content:
Now in its third edition, this classic text covers many aspects of infrared and Raman spectroscopy that are critical to the chemist doing structural or compositional analysis. This work includes practical and theoretical approaches to spectral interpretation as well as a discussion of experimental techniques. Emphasis is given to group frequencies, which are studied in detailed discussions, extensive tables, and over 600 carefully chosen and interpreted spectral examples. Also featured is a unique treatment of group frequencies that stresses their mechanical origin. This qualitative approach t
Note:
Description based upon print version of record.
,
Front Cover; Introduction to Infrared and Raman Spectroscopy; Copyright Page; Table of Contents; PREFACE; CHAPTER 1. VIBRATIONAL AND ROTATIONAL SPECTRA; 1.1 Introduction; 1.2 Photon Energy; 1.3 Degrees of Freedom of Molecular Motion; 1.4 Normal Modes of Vibration; 1.5 Mechanical Molecular Models; 1.6 Coordinates Used to Describe Molecular Vibrations; 1.7 Classical Vibrational Frequency Formula for a Diatomic Molecule; 1.8 Infrared Absorption and the Change in Dipole Moment; 1.9 Anharmonicity and Overtones; 1.10 Vibrational Potential Function; 1.11 Introduction to the Quantum Effect
,
1.12 The Quantum Mechanical Harmonic Oscillator1.13 The Boltzmann Distribution Function; 1.14 Vibrational Transitions and Infrared Absorption; 1.15 The Anharmonic Oscillator; 1.16 Combination and Difference Bands; 1.17 Fermi Resonance; 1.18 Rotation of Linear Molecules; 1.19 Rotational Transitions and Infrared Absorption; 1.20 The Nonrigid Rotator; 1.21 Rotational Line Intensities; 1.22 Types of Rotators; 1.23 Rotation of Symmetric Top Molecules; 1.24 Vibrational-Rotational Spectrum, Classical Picture; 1.25 Vibrational-Rotational Spectrum, Quantum Mechanical Treatment
,
1.26 Vibrational-Rotational Spectrum Nonrigid Rotator1.27 Spherical Top Molecules; 1.29 Asymmetrical Top Molecules; 1.30 The Raman Effect; 1.31 Polarizability; 1.32 The Tensor Character of the Polarizability; 1.33 Depolarization Ratio; 1.34 Pure Rotational Raman Spectra; 1.35 Raman Sources; CHAPTER 2. IR EXPERIMENTAL CONSIDERATIONS; 2.1 Source of Infrared Radiation; 2.2 Infrared Detectors; 2.3 Monochromators; 2.4 Interferometers; 2.5 Infrared Transmitting Materials; 2.6 Salt Polishing; 2.7 Infrared Cells; 2.8 Solid Sampling; 2.9 Internal Reflection Spectroscopy
,
2.10 Polarized Infrared Radiation2.11 Quantitative Analysis; CHAPTER 3. MOLECULAR SYMMETRY; 3.1 Symmetry Properties; 3.2 Point Groups; 3.3 Group Theory; 3.4 Group Theory Applied to Point Groups; 3.5 Representation of Groups; 3.6 Irreducible Representations; 3.7 The Character Table; 3.8 Irreducible Representation Components in a Representation; 3.9 Transformation Properties of a Vector; 3.10 The Number of Fundamentals of Each Type; 3.11 Selection Rules; 3.12 Infrared Activity of Fundamentals; 3.13 Raman Activity of Fundamentals; 3.14 Overtone and Combination Bands; 3.15 Symmetry Coordinates
,
4.15 Bend Stretch Interaction
,
English
Additional Edition:
ISBN 0-12-182554-X
Language:
English
Bookmarklink
