UID:
almafu_9958127472102883
Umfang:
1 online resource (665 p.)
ISBN:
1-299-45420-8
,
0-323-14373-3
Serie:
Porphyrins ; v. 1
Inhalt:
The Porphyrins V1
Anmerkung:
Description based upon print version of record.
,
Front Cover; The Porphyrins Volume I: Structure and Synthesis, Part A; Copyright Page; Table of Contents; List of Contributors; General Preface; Preface; Contents of Other Volumes; Chapter 1. Nomenclature; I. Introduction; II. Pyrroles; III. Systems with Two Pyrrole Rings; IV. Porphyrins and Related Compounds: The Fischer Nomenclature; V. Porphyrins and Related Compounds: A Revised Nomenclature; VI. Linear Tri- and Tetrapyrroles; VII. Ring-Contracted and Ring-Expanded Systems; VIII. Metal Complexes; Acknowledgment; References
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Chapter 2. Selected Landmarks in the History of Porphyrins and Their Biologically Functional DerivativesI. Challenge of Disease States; II. Thudichum's Cruentine (Hematoporphyrin); III. Experimental Disease States; IV. Important Books, Monographs, and Reviews; V. Conferences, Symposia, and Colloquia; VI. Determination of Iron Content of Hemoglobin (A Standard for Hemoglobinometry); VII. Crystallization of Porphyrins, Hemes, and Hemoproteins; VIII. Hemochromogens; IX. Continuum of Concepts; X. Ongoing Problems: Return to the Functional Environment of the Cell; XI. Concluding Remarks
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XII. AddendumReferences; Chapter 3. Synthesis of Porphyrins from Monopyrroles; I. Synthesis of Porphin and Chlorin; II. Synthesis of ß-Substituted Porphyrins; III. Synthesis of Meso-Substituted Porphyrins; IV. Mechanistic Considerations; V. Cis, Trarts-Dipyrrylmethene and Polypyrrylmethene Precursors; VI. Substituent Effects; VII. Cyclic Tetrapyrrole Intermediates; VIII. Conclusion; References; Chapter 4. Synthesis of Pyrroles and of Porphyrins via Single-Step Coupling of Dipyrrolic Intermediates; I. Synthesis of Pyrroles from Acyclic Precursors
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II. Manipulations of Monopyrrolic Porphyrin Precursors: Transformation of α-Substituents of 5-Methylpyrrole-2-Carboxylic EstersIII. Synthesis of Dipyrrolic Intermediates and Their Conversion to Porphyrins; IV. Appendix: Selected Examples of 2 + 2 Porphyrin Syntheses; References; Chapter 5. Synthesis of Porphyrins from 1,19-Dideoxybiladienes-ac and 1,19-Dideoxybilenes-b; I. Introduction; II. Linear Tetrapyrroles; References; Chapter 6. Synthesis of Porphyrins from Oxobilane Intermediates; I. Introduction; II. Dipyrroketones; III. Porphyrins from a-Oxobilanes; IV. Porphyrins from b-Oxobilanes
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V. Differential Protection of Pyrrole RingsVI. Synthesis of Porphyrins Bearing Labile Groups; VII. Conclusions; References; Chapter 7. Isolation and Modification of Natural Porphyrins; I. Introduction; II. Protoporphyrin and Related Natural Porphyrin Derivatives; III. Porphyrins Derived from Degradation of Chlorophylls; IV. Interconversion of Porphyrins by Chemical Means; References; Chapter 8. N-Substituted Porphyrins and Corroles; I. N-Substituted Octaalkylporphyrins; II. N-Methylated Octaethylchlorins; III. N-Alkyl-Meso-Tetraphenylporphyrins; IV. N-Alkylcorroles; V. N-Acetylcorroles
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VI. Conclusions
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English
Weitere Ausg.:
ISBN 0-12-220101-9
Sprache:
Englisch
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