UID:
almafu_9958130909902883
Umfang:
1 online resource (351 p.)
ISBN:
1-299-47230-3
,
0-323-15470-0
Serie:
Organometallic chemistry
Inhalt:
Organotransition Metal Chemistry A Mechanistic Approach
Anmerkung:
Description based upon print version of record.
,
Front Cover; Organotransition Metal Chemistry: A Mechanistic Approach; Copyright Page; Dadication; Table of Contents; Preface; Chapter I. Historical and Chemical Background; A. Development and Applications of Organotransition MetalChemistry; B. Useful Concepts; C. Ligands; D. Stereochemically Nonrigid Metal Complexes; E. Nomenclature of Coordination Compound; F. Mechanisms of Ligand Replacements; Further Reading; Chapter II. The Formation of Hydrogen and Carbon Bonds to Transition Metals; A. Methods of Preparation of Hydrido Complexes
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B. Methods of Preparation of Carbon-Transition Metal BondsFurther Reading; Chapter III. Reactions of Transition Metal σ-and π-Bonded Derivatives; A. Reactions in Which the Metal Is Retained; B. Methods for Removing Organic Groups from TransitionMetal Compounds; Further Reading; Chapter IV. Homogeneous Hydrogenation Reactions; A. Olefin Reduction; B. Homogeneous-Heterogeneous Catalysts; C. Reduction of Conjugated Dienes; D. Reduction of Ketones and Aldehydes; E. Reduction by Hydrogen Transfer; F. Dehydrogenation; Further Reading
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Chapter V. Addition and Elimination Reactions of Olefinic CompoundsA. Olefin Isomerization; B. Hydride Transfer Reactions; C. Olefin Dimerization, Oligomerization, and Polymerization; D. Vinylic and Allylic Substitution Reactions; E. Catalyzed 1:2 Additions to Olefins; Further Reading; Chapter VI. Reactions of Dienes, Trienes, and Tetraenes with Transition Metal Compounds; A. Diene π Complexes and Their Rearrangements; B. Hydride Transfer Reactions; C. Diene Reactions with Metal Hydrides; D. Proton Addition and Hydride Abstraction Reactions of Coordinated Dienes, Trienes, and Tetraenes
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E. Reactions of Coordinated Dienes with NucleophilesF. Addition Reactions of Organotransition Metal Compounds to Dienes; G. Metal-Stabilized Dienyl and Related Carbonium Ion Complexes; H. Aromatic π Complexes and Their Reactions; I. Trimethylenemethane Complexes; J. Diene Dimerization, Trimerization, and Related Reactions Further Reading; Further Reading; Chapter VII. Transition Metal Reactions with Acetylenes; A. π-Acetylenic Complexes; B. Addition Reactions of Acetylenes; C. Dimerization, Trimerization, Tetramerization, and Polymerization of Acetylenes
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D. Acetylenic Cyclizations with Incorporation of Alkyl and Aryl LigandsFurther Reading; Chapter VIII. Mixed Olefin, Diene, and Acetylene Combination Reactions; A. Olefin-Diene Reactions; B. Acetylene-Olefin Reactions; C. Acetylene-Diene Reactions; Chapter IX. Reactions of Transition Metal Complexes with Carbon Monoxide and Organic Carbonyl Compounds; A. Carbon Monoxide Reactions; B. Reactions of Organotransition Metal Complexes with Organic Carbonyl Compounds; Further Reading; Chapter X. Dinitrogen, Dioxygen, Carbene, and Sulfur Dioxide Transition Metal Complexes; A. Dinitrogen Complexes
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B. Dioxygen Complexes
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English
Weitere Ausg.:
ISBN 0-12-336150-8
Sprache:
Englisch
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