UID:
almafu_9958130327402883
Umfang:
1 online resource (216 p.)
ISBN:
1-299-31667-0
,
0-323-16000-X
Serie:
Asymmetric synthesis ; v. 1
Inhalt:
Asymmetric Synthesis V1
Anmerkung:
Description based upon print version of record.
,
Front Cover; Asymmetric Synthesis; Copyright Page; Dedication; Table of Contents; Contributors; Preface; Chapter 1. A Summary of Ways to Obtain Optically Active Compounds; I. Introduction; II. Obtaining Chiral Compounds by the FRN Method; III. Isolating Chiral Compounds from Natural Sources; IV. Resolution of Racemic Modifications by the Physical Separation of Intermediate Diastereomers; V. Asymmetric Transformations; VI. Kinetic Resolution; VII. Asymmetric Synthesis; References; Chapter 2. Polarimetry; I. Introduction; II. Instrumentation; III. Advantages of Optical Rotation Measurements
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IV. Requirements for Precision of DataReferences; Chapter 3. Competitive Reaction Methods for the Determination of Maximum Specific Rotations; I. Introduction; II. Principles of Kinetic Resolution; III. Calculation of the Specific Rotation of an Enantiomer by Means of a Method Using Asymmetric Destruction of the Corresponding Racemic Mixture; IV. Calculation of the Specific Rotation of an Enantiomer by Means of a Method Using Two Reciprocal Kinetic Resolutions; V. Conclusion; References; Chapter 4. Isotope-Dilution Techniques; I. Introduction; II. History; III. Theory; IV. Errors; V. Examples
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ReferencesChapter 5. Gas Chromatographic Methods; I. Introduction; II. Direct Resolution of Derivatized Enantiomers on Chiral Stationary Phases by Gas Chromatography; III. Direct Resolution of Underivatized Enantiomers on Metal-Containing Chiral Stationary Phases by Complexation Gas Chromatography; IV. Precision of Analysis and Practical Considerations; V. Conclusions; References; Chapter 6. Separation of Enantiomers by Liquid Chromatographic Methods; I. Introduction and Background; II. General Considerations; III. Indirect Resolutions; IV. Direct Resolutions; V. Conclusions; References
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Chapter 7. Nuclear Magnetic Resonance Analysis Using Chiral DerivativesI. Introduction; II. Application of Chemical Shift Nonequivalence; III. Application of Induced Chemical Shift Nonequivalence; References; Chapter 8. Nuclear Magnetic Resonance Analysis Using Chiral Solvating Agents; I. Introduction; II. Principles; III. Chiral Solvating Agents, Solutes, and Association Interactions; IV. Practical Experimental Considerations; V. Comparison with the Chiral Lanthanide Shift Reagent Method; VI. Conclusions; References; Chapter 9. Nuclear Magnetic Resonance Analysis Using Chiral Shift Reagents
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I. IntroductionII. General Features of Shift Reagents; III. Structural Isomerism in Chiral Shift Reagents; IV. Variations in Structure; V. Mechanism of Action; VI. Uses of Chiral Shift Reagents; VII. Experimental Procedures; References; Index
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English
Weitere Ausg.:
ISBN 0-12-507701-7
Sprache:
Englisch
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